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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cazacu, Maria
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023A Manganese(II) 3D Metal–Organic Framework with Siloxane-Spaced Dicarboxylic Ligand: Synthesis, Structure, and Propertiescitations
- 2023Fully carboxy-functionalized polyhedral silsesquioxanes as polar fillers to enhance the performance of dielectric silicone elastomerscitations
- 2022Soft silicone elastomers exhibiting large actuation strainscitations
- 2022Bentonite as an active natural filler for silicone leading to piezoelectric-like response materialcitations
- 2020Nanoscale Coordination Polymer of Dimanganese(II) as Infinite, Flexible Nanosheets with Photo‐Switchable Morphologycitations
- 2014Chemical modification of polysiloxanes with polar pendant groups by co-hydrosilylationcitations
- 2014Well-defined silicone–titania composites with good performances in actuation and energy harvestingcitations
- 2013Synthesis and characterization of silicones containing cyanopropyl groups and their use in dielectric elastomer actuatorscitations
- 2009Composite materials based on polydimethylsiloxane and <i>in situ</i> generated silica by using the sol–gel techniquecitations
- 2009Polysiloxane‐lignin compositescitations
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article
Composite materials based on polydimethylsiloxane and <i>in situ</i> generated silica by using the sol–gel technique
Abstract
<jats:title>Abstract</jats:title><jats:p>A polydimethylsiloxane‐α,ω‐diol with molar mass <jats:italic>M</jats:italic><jats:sub>n</jats:sub> = 43,000 has been synthesized by cationic polymerization of octamethylcyclotetrasiloxane and reinforced with silica. Two pathways were used for incorporation of silica in the polymeric matrix: <jats:italic>ex situ</jats:italic> by mechanical blending of a pretreated fumed silica and <jats:italic>in situ</jats:italic> by adding tetraethyl‐orthosilicate (TEOS) as silica precursor in the polymer matrix followed by their hydrolysis and condensation (sol–gel technique). The procedure occurred in the absence of solvent. Composites with different contents of silica were prepared and investigated by dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). The results were compared to those obtained on a model network based on the same polysiloxane without silica. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers</jats:p>