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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cochez, Marianne
Université de Lorraine
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2020Assessment of the protective effect of PMMA on water immersion ageing of flame retarded PLA/PMMA blendscitations
- 2020Calcium carbonate and ammonium polyphosphate flame retardant additives formulated to protect ethylene vinyl acetate copolymer against fire: Hydrated or carbonated calcium?citations
- 2019Thermal Stability and Flammability Behavior of Poly(3-hydroxybutyrate) (PHB) Based Compositescitations
- 2017Continuous-fiber-reinforced thermoplastic composites: influence of processing on fire retardant propertiescitations
- 2016Influence of modified mesoporous silica SBA-15 on the flammability of intumescent high-density polyethylenecitations
- 2016Investigation of thermal stability and flammability of poly(methyl methacrylate) composites by combination of APP with ZrO2, sepiolite or MMTcitations
- 2011Synergistic effect between hydrophobic oxide nanoparticles and ammonium polyphosphate on fire properties of poly(methyl methacrylate) and polystyrenecitations
- 2011Impact of modified alumina oxides on the fire properties of PMMA and PS nanocompositescitations
- 2010Tentative links between thermal diffusivity and fire-retardant properties in poly(methyl methacrylate)–metal oxide nanocompositescitations
- 2010Tentative links between thermal diffusivity and fire-retardant properties in poly(methyl methacrylate)emetal oxide nanocompositescitations
- 2008Influence of the surface modification of alumina nanoparticles on the thermal stability and fire reaction of PMMA compositescitations
- 2008The catalytic role of oxide in the thermooxidative degradation of poly(methyl methacrylate)–TiO2 nanocomposites
- 2003Characterization of iron substitution process in Fe:LiNbO3 single crystal fibers by polaron measurements
Places of action
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article
Influence of modified mesoporous silica SBA-15 on the flammability of intumescent high-density polyethylene
Abstract
This work aims to investigate the fire retardant properties of a novel type of high-density polyethylene composites. Our intumescent system consists in using classical flame retardants such as ammonium polyphosphate, pentaerythritol in combination with porous mesostructured silica (SBA-15) fillers. Prior to use, SBA-15 was chemically modified using different organic and inorganic grafts in order to obtain some specific properties, such as an improved compatibility with the polymer, or different types of surface acidity in order to increase charring reactions. Limiting oxygen index, UL-94, pyrolysis flow combustion calorimetry and thermogravimetric analysis were used to assess the burning behavior and thermal stability, respectively, of the processed composites. By keeping the total amount of additives always equal to 25wt%, the better flammability characteristics were in general obtained at low SBA-15 loadings (<2wt%). X-ray diffraction and Fourier transform infrared spectroscopy analyses of the residues showed that the formation of a barrier mainly constituted by crystalline silicon phosphates is probably a key to enhance the fire properties. Further slight improvements brought by the surface modification of SBA-15 nanofillers are discussed according to type of incorporated particles.