• Zainal, Nurul Fatahah Asyqin
• Yusoff, Siti Nor Hafiza Mohd
• Halim, Suhaila Idayu Abdul
• Tarmizi, Amirah Amalina Ahmad

Abstract

<jats:title>Abstract</jats:title><jats:p>The increasing demand of the functional polymers in the global industry has led to extensive development of new polymeric materials with enhanced properties. This work focuses on the effect of addition of lithium perchlorate (LiClO<jats:sub>4</jats:sub>) or titanium dioxide (TiO<jats:sub>2</jats:sub>) on the thermal properties (i.e., glass transition temperature [<jats:italic>T</jats:italic><jats:sub>g</jats:sub>], change in heat capacity [Δ<jats:italic>C</jats:italic><jats:sub>P</jats:sub>], crystallinity [<jats:italic>X</jats:italic><jats:sup>*</jats:sup>], melting temperature [<jats:italic>T</jats:italic><jats:sub>m</jats:sub>]) and morphology of poly(ethylene oxide) (PEO) investigated by using differential scanning calorimetry (DSC) and polarized optical microscope (POM). The <jats:italic>T</jats:italic><jats:sub>g</jats:sub> and Δ<jats:italic>C</jats:italic><jats:sub>P</jats:sub> of PEO at a mass fraction of salt, <jats:italic>W</jats:italic><jats:sub>S</jats:sub> ≤ 0.0196, increase with the addition of salt. Whereas the values of crystallinity and <jats:italic>T</jats:italic><jats:sub>m</jats:sub> of PEO at the same salt fraction decrease slightly with increasing salt fraction, suggesting the presence of an interaction between the salt molecules and PEO matrix. However, at <jats:italic>W</jats:italic><jats:sub>S</jats:sub> ≥ 0.107, the <jats:italic>T</jats:italic><jats:sub>g</jats:sub>, crystallinity, and <jats:italic>T</jats:italic><jats:sub>m</jats:sub> of PEO decrease significantly with the addition of salt, suggesting the phase separation of the binary mixtures of PEO and salt into salt‐rich and salt‐poor phases are developed. This observation is supported by optical inspections where the salt precipitations can be seen. Meanwhile, the values of <jats:italic>T</jats:italic><jats:sub>g</jats:sub>, Δ<jats:italic>C</jats:italic><jats:sub>P</jats:sub>, crystallinity, and <jats:italic>T</jats:italic><jats:sub>m</jats:sub> of PEO show insignificant changes with increasing nanofiller fraction indicating no interaction between PEO and the nanofiller. The two‐phase of PEO and nanofiller in the PEO‐TiO<jats:sub>2</jats:sub> can be observed clearly from the optical inspection for all PEO‐nanofiller compositions. Hence, the addition of LiClO<jats:sub>4</jats:sub> at low content exhibits relatively prominence on the PEO matrix than the TiO<jats:sub>2</jats:sub>. LiClO<jats:sub>4</jats:sub> possesses better molecular interaction with PEO than TiO<jats:sub>2</jats:sub> with PEO.</jats:p>

Topics

• impedance spectroscopy
• polymer
• phase
• glass
• glass
• glass transition temperature
• precipitation
• differential scanning calorimetry
• titanium
• Lithium
• crystallinity
• melting temperature
• heat capacity