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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lotti, Nadia
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Critical Cooling Rate of Fast-Crystallizing Polyesters: The Example of Poly(alkylene trans-1,4-cyclohexanedicarboxylate)citations
- 2024Melting Behavior of Compression Molded Poly(ester amide) from 2,5-Furandicarboxylic Acid
- 2023Novel Nanostructured Scaffolds of Poly(butylene trans-1,4-cyclohexanedicarboxylate)-Based Copolymers with Tailored Hydrophilicity and Stiffness: Implication for Tissue Engineering Modelingcitations
- 2022Electrospun Membranes of Poly(butylene succinate) and Poly(butylene/2‐butyl,2‐ethyl‐propylene succinate)citations
- 2022Bio-based aliphatic/aromatic poly(trimethylene furanoate/sebacate) random copolymers:Correlation between mechanical, gas barrier performances and compostability and copolymer compositioncitations
- 2021Poly(butylene 2,4-furanoate), an Added Member to the Class of Smart Furan-Based Polyesters for Sustainable Packaging : Structural Isomerism as a Key to Tune the Final Propertiescitations
- 2020Ability of Trichoderma hamatum Isolated from Plastics-Polluted Environments to Attack Petroleum-Based, Synthetic Polymer Filmscitations
- 2020Broadband Dielectric Spectroscopy Study of Biobased Poly(alkylene 2,5-furanoate)s’ Molecular Dynamicscitations
- 2020Stability of crystal nuclei of poly (butylene isophthalate) formed near the glass transition temperature
- 2020Improving the flexibility and compostability of starch/poly(butylene cyclohexanedicarboxylate)-based blendscitations
- 2020Enthalpy relaxation, crystal nucleation and crystal growth of biobased poly(butylene isophthalate)citations
- 2020Broadband dielectric spectroscopy study of biobased poly(alkylene 2,5-furanoate)s’ molecular dynamicscitations
- 2018Influence of the nanofiber chemistry and orientation of biodegradable poly(butylene succinate)-based scaffolds on osteoblast differentiation for bone tissue regenerationcitations
- 2018Crystallization of isodimorphic aliphatic random copolyesters: Pseudo-eutectic behavior and double-crystalline materialscitations
- 2018Cold-crystallization of poly(butylene 2,6-naphthalate) following Ostwald's rule of stagescitations
- 2018Crystallization of isodimorphic aliphatic random copolyesters: pseudo-eutectic behavior and double-crystalline materialscitations
- 2018Characterization of Active Edible Films based on Citral Essential Oil, Alginate and Pectincitations
- 2017Novel Random PBS-Based Copolymers Containing Aliphatic Side Chains for Sustainable Flexible Food Packagingcitations
- 2014Poly(propylene terephthalate) containing 4,4-sulfonylbisphenol units:effect of chemical composition on the physical-chemical propertiescitations
- 2013Towards homogeneous dynamics in incompatible blends by selective transesterificationcitations
- 2010Structure and morphology of thin films of linear aliphatic polyesters prepared by spin-coatingcitations
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article
Electrospun Membranes of Poly(butylene succinate) and Poly(butylene/2‐butyl,2‐ethyl‐propylene succinate)
Abstract
Poly(butylene succinate) (PBS) and poly(butylene/2-butyl,2-ethyl-propylene succinate) (PBSBEPS) membranes are prepared by electrospinning technique. In recent years, interest in biodegradable aliphatic polyesters, including PBS and its copolymers, is increasing as they have potential applications in various sectors such as mulching films, food packaging, tissue engineering, and drug delivery. In this work, the synthesized polymers are dissolved in different solvents, namely acetone, chloroform (CHCl3), methanol, dichloromethane (DCM), and dimethylformamide in order to obtain the best solvent system. These solutions are then electrospun at room temperature to produce micron-sized fibers. The variables examined in determining the optimal solution and electrospinning conditions are the solvent system used, the concentration of PBS and PBS-based random copolymer, applied voltage, flow rate, humidity, and the distance between the needle tip and the collector, all of which have a meaningful effect on the fiber morphology. Among the various solvents used, the DCM and the less toxic CHCl3 result in fewer bead defects among fibers. Besides, an increase in PBS and PBS-based random copolymer concentration determines the reduction of bead defects, which from 12 to 14 wt% results in bead-free uniform fibers, when suitable processing parameters are set. Promising results, which can pave the way for the production of membranes loaded with appropriate anticancer molecules for targeted biomedical applications, are obtained.