• Charitidis, Costas
• Dragatogiannis, Dimitris
• Plakantonaki, Niki
• Trapalis, Christos
• Ntziouni, Afroditi
• Bakola, Veroniki
• Kiparissides, Costas
• Kotrotsiou, Olympia

Abstract

<jats:title>Abstract</jats:title><jats:p>Novel two‐layer nanostructured electrodes are successfully prepared for their application in membrane capacitive deionization (MCDI) processes. Nanostructured carbonaceous materials such as graphene oxide (GO) and carbon nanotubes (CNTs), as well as activated carbon (AC) are dispersed in a solution of poly(vinyl alcohol) (PVA), mixed with polyacrylic acid (PAA) or polydimethyldiallylammonium chloride (PDMDAAC), and subsequently cast on the top surface of an AC‐based modified graphite electrode to form a thin composite layer that is cross‐linked with glutaraldehyde (GA). Cyclic voltammetry (CV) is performed to investigate the electrochemical properties of the composite electrodes and desalination experiments are conducted in batch mode using a MCDI unit cell to investigate the effects of i) the nanostructured carbonaceous material, ii) its concentration in the polymer blend, and iii) the molecular weight of the polymers on the desalination efficiency of the system. Comparative studies with commercial membranes are performed proving that the composite nanostructured electrodes are more efficient in salt removal. The improved performance of the composite electrodes is attributed to the ion exchange properties of the selected polymers and the increased specific capacitance of the nanostructured carbonaceous materials. This research paves the way for wider application of MCDI in water desalination.</jats:p>

Topics

• impedance spectroscopy
• surface
• Carbon
• experiment
• nanotube
• composite
• molecular weight
• alcohol
• cyclic voltammetry
• polymer blend
• deionisation method