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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Muellen, Klaus
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Single-Layered Imine-Linked Porphyrin-Based Two-Dimensional Covalent Organic Frameworks Targeting CO<sub>2</sub> Reductioncitations
- 2020Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditionscitations
- 2017Persulfurated Coronene: A New Generation of "Sulflower"citations
- 2017A Stable Saddle-Shaped Polycyclic Hydrocarbon with an Open-Shell Singlet Ground Statecitations
- 2017Polycyclic heteroaromatic hydrocarbons containing a benzoisoindole corecitations
- 2016Synthesis of NBN-Type Zigzag-Edged Polycyclic Aromatic Hydrocarbons: 1,9-Diaza-9a-boraphenalene as a Structural Motifcitations
- 2015Emission Turn-On and Solubility Turn-Off in Conjugated Polymerscitations
- 2014Squeezing, Then Stacking: From Breathing Pores to Three-Dimensional Ionic Self-Assembly under Electrochemical Controlcitations
- 2012Nitrogen-Doped Graphene and Its Iron-Based Composite As Efficient Electrocatalysts for Oxygen Reduction Reactioncitations
- 2011Energy Transfer Pathways in a Rylene-Based Triadcitations
Places of action
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article
Emission Turn-On and Solubility Turn-Off in Conjugated Polymers
Abstract
<p>The synthesis of highly efficient two-photon uncaging groups and their potential use in functional conjugated polymers for post-polymerization modification are reported. Careful structural design of the employed nitrophenethyl caging groups allows to efficiently induce bond scission by a two-photon process through a combination of exceptionally high two-photon absorption cross-sections and high reaction quantum yields. Furthermore, -conjugated polyfluorenes are functionalized with these photocleavable side groups and it is possible to alter their emission properties and solubility behavior by simple light irradiation. Cleavage of side groups leads to a turn-on of the fluorescence while solubility of the -conjugated materials is drastically reduced.</p>