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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Picken, S. J.
Delft University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Role of Molecular Water Layer State on Freezing Front Propagation Rate and Mode Studied with Thermal Imagingcitations
- 2023Affine Deformation and Self-Assembly Alignment in Hydrogel Nanocomposites
- 2023Affine Deformation and Self-Assembly Alignment in Hydrogel Nanocomposites
- 2023Enhancing the sensitivity of silicon photonic ultrasound sensors by optimizing the stiffness of polymer cladding
- 2022Extraction of low molecular weight polyhydroxyalkanoates from mixed microbial cultures using bio-based solventscitations
- 2022High-Strength Liquid Crystal Polymer-Graphene Oxide Nanocomposites from Watercitations
- 2016Water Sorption and Diffusion in (Reduced) Graphene Oxide-Alginate Biopolymer Nanocompositescitations
- 2016Composition dependent properties of graphene (oxide)-alginate biopolymer nanocompositescitations
- 2016Rheological investigation of specific interactions in Na Alginate and Na MMT suspensioncitations
- 2015Origin of highly ordered sodium alginate/montmorillonite bionanocompositescitations
- 2013Self-healing supramolecular polymer nanocomposites
- 2011Three-phase Lewis-Nielsen model for the thermal conductivity of polymer nanocompositescitations
- 2009Thermal behaviour of epoxy resin filled with high thermal conductivity nanopowderscitations
- 2007Vapor diffusion in porous/nonporous polymer coatings by dielectric sorption analysiscitations
- 2005Multiple glass transitions in the plastic crystal phase of triphenylene derivatescitations
- 2000Highly ordered side-chain liquid-crystalline polymers from maleic anhydride and swallow-tailed 1-alkenes having two mesogens
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article
Water Sorption and Diffusion in (Reduced) Graphene Oxide-Alginate Biopolymer Nanocomposites
Abstract
<p>The water sorption and diffusion in (reduced) graphene oxide-alginate composites of various compositions is analyzed. Water sorption of sodium alginate can be significantly reduced by the inclusion of graphene oxide sheets due to the formation of an extensive hydrogen bonding network between oxygenated groups. Crosslinking alginate with divalent metal ions and the presence of reduced graphene oxide can further improve the swelling resistance due to the strong interactions between metal ions, alginate, and filler sheets. Depending on conditions and composition, the overall water barrier properties of alginate composites improve upon (reduced) graphene oxide filling, making them attractive for moisture barrier coating applications. Water sorption kinetics in all alginate composites indicate a non-Fickian diffusion process that can be accurately described by the Variable Surface Concentration model. In addition, the water barrier properties of sodium alginate-graphene oxide composites can be adequately predicted using a simple model that takes the orientational order of filler sheets and their effective aspect ratio into account. (Figure presented.).</p>