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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Stoclet, Grégory
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Topics
Publications (14/14 displayed)
- 2023Structure And Mechanical Behavior of Fully Substituted Acid Starch Esterscitations
- 2022Effect of chain orientation on the brittle to ductile transition in Polylactide
- 2022Novel family of polylactide-based copolymer matrix composites by RTM process
- 2022Hydrolytic degradation of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) - Towards an understanding of microplastics fragmentationcitations
- 2022Unprecedented polylactide-based copolymer matrix composites by Resin Transfer Molding
- 2021Comparative studies of thermal and mechanical properties of macrocyclic versus linear polylactidecitations
- 2021Poly(lactide)/cellulose nanocrystal nanocomposites by high‐shear mixingcitations
- 2021Poly(lactide)/cellulose nanocrystal nanocomposites by high-shear mixingcitations
- 2020Comparative studies of thermal and mechanical properties of macrocyclic versus linear polylactidecitations
- 2019Effect of surface modification of colloidal silica nanoparticles on the rigid amorphous fraction and mechanical properties of amorphous polyurethane–urea–silica nanocompositescitations
- 2019Water–Soluble Extracts from Banana Pseudo–stem as Functional Additives for Polylactic Acid: Thermal and Mechanical Investigationscitations
- 2018Processing of PVDF-based electroactive/ferroelectric films: importance of PMMA and cooling rate from the melt state on the crystallization of PVDF beta-crystalscitations
- 2015Comparison of the influence of talc and kaolinite as inorganic fillers on morphology, structure and thermomechanical properties of polylactide based compositescitations
- 2014Isoprene-Styrene Chain Shuttling Copolymerization Mediated by a Lanthanide Half-Sandwich Complex and a Lanthanidocene: Straightforward Access to a New Type of Thermoplastic Elastomerscitations
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article
Structure And Mechanical Behavior of Fully Substituted Acid Starch Esters
Abstract
International audience ; This study deals with the evolution of structural, thermal, and mechanical properties of a series of fully substituted fatty acid starch esters (FASEs) according to side chain length (from 2 (C2) up to 16 (C16) Carbons). FASEs with C2 to C12 side chains are fully amorphous with a glass transition temperature depending on chain length while in the case of FASE with C16 side chains, a part of side chains is able to crystallize. Thermomechanical behavior depends strongly on both the alkyl chain length and crystallinity of samples. In particular, for FASE-C16, the presence of crystals leads to a brittle behavior. During stretching, no macromolecular orientation is evidenced for short-chain FASEs (<C8), whereas, for long-chain starch ester from C8 to C16 length, an orientation of starch backbone in the drawing direction is observed.