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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Marchese, Paola
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Valorization of coffee silverskin by cascade extraction of valuable biomolecules: preparation of eco‐friendly composites as the ultimate stepcitations
- 2023From Biomass to Bio‐Based Polymers: Exploitation of Vanillic Acid for the Design of New Copolymers with Tunable Propertiescitations
- 2022A contribution to the circular economy concept: biocomposites based on fully valorized agro-industrial residues.
- 2020Polymorphism and Multiple Melting Behavior of Bio-Based Poly(propylene 2,5-furandicarboxylate)citations
- 2020Eco-Conversion of Two Winery Lignocellulosic Wastes into Fillers for Biocomposites: Vine Shoots and Wine Pomacescitations
- 2016Strategy to Modify the Crystallization Behavior of EVOH32 through Interactions with Low-Molecular-Weight Moleculescitations
- 2016Photodegradation of TiO2 composites based on polyesters.citations
- 2016Photodegradation of TiO2 composites based on polyesterscitations
- 2015Use of ionic liquids based on phosphonium salts for preparing biocomposites by in situ polymerizationcitations
- 2014Poly(1,4-dimethylcyclohexane adipate) nanocomposites with organoclays modified with ionic liquid based on phosphonium salt
- 2012Photodegradation of aliphatic polyesters and their composites with TiO2
Places of action
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article
From Biomass to Bio‐Based Polymers: Exploitation of Vanillic Acid for the Design of New Copolymers with Tunable Properties
Abstract
Vanillic acid represents a potentially interesting bio-based building block for the production of new aliphatic-aromatic polymers, characterized by thermal properties similar to those of the analogous terephthalic polyesters. However, poly(ethylene vanillate) proved to be a very brittle material, probably due to a very high degree of crystallinity, and, then, not suitable for melt processing. Therefore, the synthesis of copolymers, based on vanillic acid and pentadecalactone is considered as a strategy to obtain new polymeric materials with a low degree of crystallinity, tunable properties, and better performances. The synthesis of these fully bio-based random copolymers is successful. The thermal properties have been studied in order to correlate chemical structure and final performances. The polymers proved to be processable and films are obtained, suggesting possible applications of the copolymers in a new sustainable flexible packaging.