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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vannini, Micaela
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Valorization of coffee silverskin by cascade extraction of valuable biomolecules: preparation of eco‐friendly composites as the ultimate stepcitations
- 2023From Biomass to Bio‐Based Polymers: Exploitation of Vanillic Acid for the Design of New Copolymers with Tunable Propertiescitations
- 2022A contribution to the circular economy concept: biocomposites based on fully valorized agro-industrial residues.
- 2021Bio-based furan-polyesters/graphene nanocomposites prepared by in situ polymerizationcitations
- 2020Polymorphism and Multiple Melting Behavior of Bio-Based Poly(propylene 2,5-furandicarboxylate)citations
- 2020Eco-Conversion of Two Winery Lignocellulosic Wastes into Fillers for Biocomposites: Vine Shoots and Wine Pomacescitations
- 2018Bio-Based PA11/Graphene Nanocomposites Prepared by In Situ Polymerizationcitations
- 2016Potential use of rice endosperm fibers as reinforcing material in biocomposites
- 2016Multicomponent reinforcing system for poly(butylene succinate): Composites containing poly(l-lactide) electrospun mats loaded with graphenecitations
- 2016Strategy to Modify the Crystallization Behavior of EVOH32 through Interactions with Low-Molecular-Weight Moleculescitations
- 2016Evaluation of the retting process as a pre-treatment of vegetable fibers for the preparation of high-performance polymer biocompositescitations
- 2012TiO2 deposition on the surface of activated fluoropolymer substratecitations
- 2012TiO2 deposition on the surface of activated fluoropolymer substrate
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article
From Biomass to Bio‐Based Polymers: Exploitation of Vanillic Acid for the Design of New Copolymers with Tunable Properties
Abstract
Vanillic acid represents a potentially interesting bio-based building block for the production of new aliphatic-aromatic polymers, characterized by thermal properties similar to those of the analogous terephthalic polyesters. However, poly(ethylene vanillate) proved to be a very brittle material, probably due to a very high degree of crystallinity, and, then, not suitable for melt processing. Therefore, the synthesis of copolymers, based on vanillic acid and pentadecalactone is considered as a strategy to obtain new polymeric materials with a low degree of crystallinity, tunable properties, and better performances. The synthesis of these fully bio-based random copolymers is successful. The thermal properties have been studied in order to correlate chemical structure and final performances. The polymers proved to be processable and films are obtained, suggesting possible applications of the copolymers in a new sustainable flexible packaging.