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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Jordan, Rainer
in Cooperation with on an Cooperation-Score of 37%
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Publications (6/6 displayed)
- 2021A molecular brush with thermoresponsive poly(2-ethyl-2-oxazoline) side chains: a structural investigationcitations
- 2018Polymerization driven monomer passage through monolayer chemical vapour deposition graphenecitations
- 2017In-Situ Stretching Patterned Graphene Nanoribbons in the Transmission Electron Microscopecitations
- 2015Lateral damage in graphene carved by high energy focused gallium ion beamscitations
- 2010Poly(2-(dimethylamino)ethyl methacrylate) brushes with incorporated nanoparticles as a SERS active sensing layercitations
- 2008Micellar Structures of Hydrophilic/Lipophilic and Hydrophilic/Fluorophilic Poly(2-oxazoline) Diblock Copolymers in Watercitations
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article
Micellar Structures of Hydrophilic/Lipophilic and Hydrophilic/Fluorophilic Poly(2-oxazoline) Diblock Copolymers in Water
Abstract
Amphiphilic poly(2-alkyl-2-oxazoline) diblock copolymers of 2-methyl-2-oxazoline (MOx) building the hydrophilic block and either 2-nonyl-2-oxazoline (NOx) for the hydrophobic or 2-(1H,1H,2H,2H-perfluorohexyl)-2-oxazoline (FOx) for the fluorophilic block were synthesized by sequential living cationic polymerization. The polymer amphiphiles form core/shell micelles in aqueous solution as evidenced using small-angle neutron scattering (SANS). Whereas the diblock copolymer micelles with a hydrophobic NOxn block are spherical, the micelles with the fluorophilic FOxn are slightly elongated, as observed by SANS and TEM. In water, the micelles with fluorophilic and lipophilic cores do not mix, but coexist.