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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Crusset, Didier
Agence Nationale pour la Gestion des Déchets Radioactifs
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2021Mechanisms of localized corrosion of carbon steel associated with magnetite/mackinawite layers in a cement groutcitations
- 2021Corrosion behavior of aluminum alloy 5754 in cement‐based matrix‐simulating nuclear waste disposal conditionscitations
- 2021Potential influence of microorganisms on the corrosion of carbon steel in the French high‐ and intermediate‐level long‐lived radioactive waste disposal contextcitations
- 2021Formation of iron sulfides on carbon steel in a specific cement grout designed for radioactive waste repository and associated corrosion mechanismscitations
- 2021Stress corrosion cracking susceptibility of P285NH and API 5L X65 steel grades in the high‐level radioactive waste repository cell conceptcitations
- 2020A study by electrochemical impedance spectroscopy and surface analysis of corrosion product layers formed during CO2 corrosion of low alloy steelcitations
- 2019Long-term corrosion behaviour of carbon steel and stainless steel in Opalinus clay: influence of stepwise temperature increasecitations
- 2017Electrochemical behaviour of non-alloy steel reinforcement in alkaline solutions
- 2017Bio-corrosion detection by sulphur isotopic fractionation measurements using nanoSIMS
- 2005Use of ion beam analysis techniques to characterise iron corrosion under water radiolysis
- 2000Thermal iodine release of surface implanted iodine in zirconia and its affect on hull disposalcitations
Places of action
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article
Mechanisms of localized corrosion of carbon steel associated with magnetite/mackinawite layers in a cement grout
Abstract
<jats:title>Abstract</jats:title><jats:p>Carbon steel electrodes covered with a specific low‐pH cement grout (pH ~10.7 at 20°C), designed for nuclear waste management applications, were immersed for 30 days in a 0.01‐M NaCl + 0.01‐M NaHCO<jats:sub>3</jats:sub> solution (pH 7 measured at 20°C), in aerated conditions, at 80°C. The corrosion processes were studied by voltammetry and linear polarization resistance measurements while the corrosion product layers were analyzed by µ‐Raman spectroscopy and X‐ray diffraction. Most of the electrodes (75%) suffered from localized corrosion, a phenomenon associated with the formation of a heterogeneous Fe<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>/FeS layer. It is proposed that the mechanisms of the particular corrosion process observed here are associated with galvanic effects, the large magnetite‐covered zone acting as cathode and the locally mackinawite‐covered zones being anodic regions.</jats:p>