| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pielichowski, Krzysztof
Cracow University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Thermoplastic polyurethane POSS nanohybrids: Synthesis, morphology, and biological propertiescitations
- 2023Tailoring the physical properties of non-isocyanate polyurethanes by introducing secondary amino groups along their main chaincitations
- 2020Compression-Induced Phase Transitions of Bicalutamidecitations
- 2020Measurement methodology toward determination of structure-propertyrelationships in acrylic hydrogels with starch and nanogold designed forbiomedical applicationscitations
- 2019Morphology, dynamics, and order development in a thermoplastic polyurethane with melt blended POSScitations
- 2018The effect of surface modification of microfibrillated cellulose (MFC) by acid chlorides on the structural and thermomechanical properties of biopolyamide 4.10 nanocomposites
- 2014Characterization of synthesized polyurethane/montmorillonite nanocomposites foams.citations
- 2014Effect of nanofillers on low energy impact performance of sandwich structures with nanoreinforced polyurethane foam cores.citations
- 2013Polyurethanes modified with functionalized silsesquioxane - Synthesis and propertiescitations
- 2013The Influence of Multiscale Fillers Rein forcement into Impact Resistance and Energy Absorption Properties of Polyamide 6 and Polypropylene Nanocomposite Structurescitations
- 2012Physical characteristics of nanoparticles emitted during drilling of silica based polyamide 6 nanocomposites.citations
- 2012The effect of nanoclay on dust generation during drilling process of polyamide 6 nanocompositescitations
- 2012The effect of nanoclay on dust generation during drilling of PA6 nanocomposites.citations
- 2012The Effect of Nanoclay on Dust Generation during Drilling of PA6 Nanocompositescitations
- 2007Epoxy-based fibre reinforced nanocompositescitations
- 2007Polymer/montmorillonite nanocomposites with improved thermal properties: Part I. Factors influencing thermal stability and mechanisms of thermal stability improvement.citations
Places of action
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article
Thermoplastic polyurethane POSS nanohybrids: Synthesis, morphology, and biological properties
Abstract
<jats:title>Abstract</jats:title><jats:p>Recent studies show good osteoinductive properties of polyurethanes modified with polyhedral oligomeric silsesquioxanes (POSS). In this work, three types of POSS; propanediolisobutyl‐POSS (PHI‐POSS), disilanolisobutyl‐POSS (DSI‐POSS), and octahydroxybutyl‐POSS (OCTA‐POSS) were chemically incorporated into linear polyurethane based on an aliphatic isocyanate, hexamethylene diisocyanate (HDI), to obtain new nanohybrid PU‐POSS materials. The full conversion of POSS was confirmed by Fourier transform infrared spectroscopy (FTIR‐ATR) spectra of the model reactions with pure HDI. The materials obtained were investigated by FTIR, SEM‐EDS, and DSC. The DSC studies showed the thermoplasticity of the obtained materials and apparently good recovery. 30‐day immersion in SBF (simulated body fluid) revealed an increase in the rate of deposition of hydroxyapatite (HAp) for the highest POSS loadings, resulting in thick layers of hydroxyapatite (~60–40 μm), and the Ca/P ratio 1.67 (even 1.785). The structure and properties of the inorganic layer depend on the type of POSS, the number of hard segments, and those containing POSS, which can be tailored by changing the HDI/poly(tetramethylene glycol) (PTMG) ratio. Furthermore, the obtained composites revealed good biocompatibility, as confirmed by cytotoxicity tests conducted on two cell lines; normal human dermal fibroblasts (NHDF) and primary human osteoblasts (HOB). Adherent cells seeded on the tested materials showed viability even after a 48‐h incubation. After this time, the population of viable, and proliferating cells exceeded 90%. Bioimaging studies have shown the fibroblast and osteoblast cells were well attached to the surface of the tested materials.</jats:p>