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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Shanaghi, Ali
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2021Enhanced corrosion resistance and reduced cytotoxicity of the AZ91 Mg alloy by plasma nitriding and a hierarchical structure composed of ciprofloxacin-loaded polymeric multilayers and calcium phosphate coatingcitations
- 2021Corrosion resistance, nano-mechanical properties, and biocompatibility of Mg-plasma-implanted and plasma-etched Ta/TaN hierarchical multilayered coatings on the nitrided AZ91 Mg alloycitations
- 2021Enhanced corrosion resistance, antibacterial properties, and biocompatibility by hierarchical hydroxyapatite/ciprofloxacin-calcium phosphate coating on nitrided NiTi alloycitations
- 2021Effects of the tantalum intermediate layer on the nanomechanical properties and biocompatibility of nanostructured tantalum/tantalum nitride bilayer coating deposited by magnetron sputtering on the nickel titanium alloycitations
- 2020EIS and noise study of zirconia-alumina- benzotriazole nano-composite coating applied on Al2024 by the sol-gel methodcitations
- 2019Effect of Ti interlayer on corrosion behavior of nanostructured Ti/TiN multilayer coating deposited on TiAl<sub>6</sub>V<sub>4</sub>citations
- 2019Improved corrosion behavior of DLC-coated AZ91 Mg
- 2019Nano-mechanical properties of zirconia-alumina-benzotriazole nano-composite coating deposited on Al2024 by the sol-gel methodcitations
- 2019Effects of Benzotriazole on nano-mechanical properties of zirconia-alumina-Benzotriazole nanocomposite coating deposited on Al 2024 by the sol-gel methodcitations
- 2018Effects of silica and Ag on the electrochemical behavior of titania-based nanocomposite coatings deposited on 2024 aluminum alloy by the sol-gel methodcitations
- 2018Improving of tribology properties of TiAl6V4 with nanostructured Ti/TiN-multilayered coating deposited by high-vacuum magnetron sputteringcitations
- 2017Effect of Inhibitor Agents Addition on Corrosion Resistance Performance of Titania Sol–Gel Coatings Applied on 304 Stainless Steelcitations
- 2017Corrosion behavior of reactive sputtered Ti/TiN nanostructured coating and effects of intermediate titanium layer on self-healing propertiescitations
- 2017Nano mechanical and wear properties of multi-layer Ti/TiN coatings deposited on Al 7075 by high-vacuum magnetron sputteringcitations
- 2012Effect of plasma CVD operating temperature on nanomechanical properties of TiC nanostructured coating investigated by atomic force microscopycitations
- 2012Effects of duty cycle on microstructure and corrosion behavior of TiC coatings prepared by DC pulsed plasma CVDcitations
- 2011Improved tribological properties of TiC with porous nanostructured TiO 2 intermediate layercitations
Places of action
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article
Enhanced corrosion resistance and reduced cytotoxicity of the AZ91 Mg alloy by plasma nitriding and a hierarchical structure composed of ciprofloxacin-loaded polymeric multilayers and calcium phosphate coating
Abstract
Much effort has made to lessen the cytotoxicity and enhance the corrosion resistance of biodegradable magnesium alloys, for example, by depositing multilayered polymeric coatings containing hydroxyapatite. In this work, a hierarchical structure composed of ciprofloxacin (Cip)-loaded on polyacrylic acid (PAA) and poly (ethyleneimine) (PEI) as biocompatible polymeric multilayers and calcium phosphate coating as the top layer is formed by the sol–gel method on the AZ91 Mg alloy with an intermediate layer formed by nitrogen plasma immersion ion implantation. The thicknesses of the multilayered coating and nitrided layer (Mg<sub>3</sub>N<sub>2</sub>) are 10 μm and 140 nm, respectively. The corrosion current density decreases by 95.6% and the corrosion potential in the polarization curve shifts to the positive direction by 23%. The passivation process which occurs at defects by deposition of corrosion products mitigates both galvanic and localized corrosion. Slight increase in the contact angle and surface free energy, enhanced corrosion resistance, and reduced cytotoxicity are observed from the multilayered structure. The better corrosion resistance enables better control of release of Cip. Biological assessment indicates that the antibacterial activity against <i>Escherichia coli</i> is improved by 100% after culturing for 24 hr and the cell viability and noncytotoxic behavior of the coated AZ91 are enhanced as well. The corrosion behavior and biological results suggest that the strategy of using a hierarchical structure composed of Cip-loaded polymeric multilayers in conjunction with an intermediate plasma nitrided layer has large potential in the development of biodegradable orthopedic implants made of Mg alloys.