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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Boehme, Simon C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Size- and temperature-dependent lattice anisotropy and structural distortion in CsPbBr 3 quantum dots by reciprocal space X-ray total scattering analysiscitations
- 2024Quantifying the Size‐Dependent Exciton‐Phonon Coupling Strength in Single Lead‐Halide Perovskite Quantum Dotscitations
- 2024Quantifying the size-ddependent exciton-phonon coupling strength in single lead-halide perovskite quantum dotscitations
- 2024Quantifying Förster resonance energy transfer from single perovskite quantum dots to organic dyescitations
- 2024Designer phospholipid capping ligands for soft metal halide nanocrystalscitations
- 2023Strongly Confined CsPbBr3 Quantum Dots as Quantum Emitters and Building Blocks for Rhombic Superlatticescitations
- 2023Strongly Confined CsPbBr3 Quantum Dots as Quantum Emitters and Building Blocks for Rhombic Superlattices.
- 2023Size‐ and Temperature‐Dependent Lattice Anisotropy and Structural Distortion in CsPbBr<sub>3</sub> Quantum Dots by Reciprocal Space X‐ray Total Scattering Analysiscitations
- 2023Strongly confined CsPbBr 3 quantum dots as quantum emitters and building blocks for rhombic superlatticescitations
- 2023Designer Phospholipid Capping Ligands for Soft Metal Halide Nanocrystalscitations
- 2021Correlating Ultrafast Dynamics, Liquid Crystalline Phases, and Ambipolar Transport in Fluorinated Benzothiadiazole Dyescitations
- 2021Pressure-induced perovskite-to-non-perovskite phase transition in CsPbBr 3citations
- 2021Pressure‐Induced Perovskite‐to‐non‐Perovskite Phase Transition in CsPbBr<sub>3</sub>citations
- 2021Synthesis and characterization of the ternary nitride semiconductor Zn 2 VN 3 : theoretical prediction, combinatorial screening, and epitaxial stabilizationcitations
- 2021Hybrid 0D antimony halides as air-stable luminophores for high-spatial-resolution remote thermographycitations
- 2018Extraordinary Interfacial Stitching between Single All-Inorganic Perovskite Nanocrystalscitations
- 2018Extraordinary Interfacial Stitching between Single All-Inorganic Perovskite Nanocrystalscitations
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article
Pressure‐Induced Perovskite‐to‐non‐Perovskite Phase Transition in CsPbBr<sub>3</sub>
Abstract
<jats:title>Abstract</jats:title><jats:p>The expanding range of optoelectronic applications of lead‐halide perovskites requires their production in diverse forms (single crystals, thin‐ and thick‐films or even nanocrystals), motivating the development of diverse materials processing and deposition routes that are specifically suited for these structurally soft, low‐melting semiconductors. Pressure‐assisted deposition of compact pellets or thick‐films are gaining popularity, necessitating studies on the pressure effects on the atomic structure and properties of the resulting material. Herein we report the phase transformation in bulk polycrystalline cesium lead bromide from its three‐dimensional perovskite phase (γ‐CsPbBr<jats:sub>3</jats:sub>) into the one‐dimensional polymorph (δ‐CsPbBr<jats:sub>3</jats:sub>) upon application of hydrostatic pressure (0.35 GPa). δ‐CsPbBr<jats:sub>3</jats:sub> is characterized by a wide bandgap of 2.9 eV and broadband yellow luminescence at 585 nm (2.1 eV) originating from self‐trapped excitons. The formation of δ‐CsPbBr<jats:sub>3</jats:sub> was confirmed and characterized by <jats:italic>Raman</jats:italic> spectroscopy, <jats:sup>207</jats:sup>Pb and <jats:sup>133</jats:sup>Cs solid‐state nuclear magnetic resonance, X‐ray diffraction, absorption spectroscopy, and temperature‐dependent and time‐resolved photoluminescence spectroscopy. No such phase transition was observed in colloidal CsPbBr<jats:sub>3</jats:sub> nanocrystals.</jats:p>