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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rahman, Saidur
Lancaster University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023Thermo-kinetic behaviour of green synthesized nanomaterial enhanced organic phase change material : Model fitting approach
- 2022Hydrogen-rich syngas production from bi-reforming of greenhouse gases over zirconia modified Ni/MgO catalystcitations
- 2022Improved thermo-physical properties and energy efficiency of hybrid PCM/graphene-silver nanocomposite in a hybrid CPV/thermal solar systemcitations
- 2022Potent antibacterial activity of MXene–functionalized graphene nanocomposites
- 2021Optimization of thermophysical and rheological properties of mxene ionanofluids for hybrid solar photovoltaic/thermal systemscitations
- 2021ANN Modeling of Thermal Conductivity and Viscosity of MXene-Based Aqueous IoNanofluidcitations
- 2021Back propagation modeling of shear stress and viscosity of aqueous Ionic-MXene nanofluidscitations
- 2021Analysis of Multiwalled Carbon Nanotubes Porosimetry And Their Thermal Conductivity with Ionic Liquid-Based Solventscitations
- 2020Experimental investigation of energy storage properties and thermal conductivity of a novel organic phase change material/MXene as A new class of nanocompositescitations
- 2020Experimental investigation of energy storage properties and thermal conductivity of a novel organic phase change material/MXene as A new class of nanocompositescitations
- 2020Effect of al2o3 dispersion on enthalpy and thermal stability of ternary nitrate eutectic salt
- 2020Experimental assessment of a novel eutectic binary molten salt-based hexagonal boron nitride nanocomposite as a promising PCM with enhanced specific heat capacitycitations
- 2020New magnetic Co3O4/Fe3O4 doped polyaniline nanocomposite for the effective and rapid removal of nitrate ions from ground water samplescitations
- 2019Experimental investigation of thermal stability and enthalpy of eutectic alkali metal solar salt dispersed with MGO nanoparticlescitations
- 2019Crosslinked thermoelectric hydro-ionogelscitations
- 2019The influence of covalent and non-covalent functionalization of GNP based nanofluids on its thermophysical, rheological and suspension stability propertiescitations
- 2018Conducting polymers
Places of action
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article
Hydrogen-rich syngas production from bi-reforming of greenhouse gases over zirconia modified Ni/MgO catalyst
Abstract
Bi-reforming of methane (BRM) is gaining an increase interest due to the critical requirements to mitigate global warming and provide alternative energy resources. However, there has been a serious challenge to the scale-up of the process to commercial production due to the catalyst deactivation. In the present study, the influence of ZrO2 modifications on the activity and stability of MgO-supported Ni catalyst in the BRM reaction was investigated. The ZrO2-MgO mixed oxide support was prepared by co-precipitation method with variation in the ZrO2 composition and subsequently impregnated with Ni. The characterization of the freshly prepared Ni/MgO and Ni/MgO-ZrO2 catalysts using N2 physisorption analysis, X-Ray Diffraction (XRD), FESEM, XPS, H2-TPR, and CO2-TPD techniques revealed suitable physicochemical properties for the BRM reaction. The Ni/MgO-ZrO2 catalysts showed an improved performance in the BRM reaction in terms of activity and stability compared to the Ni/MgO at 800°C and CH4, H2O, CO2 ratio of 3:2:1, respectively. The best performance was obtained using the Ni/15%ZrO2-MgO for the BRM with CO2 and CH4 conversion of 81.5% and 82.5%, respectively. The characterization of the spent Ni/MgO catalyst using Raman spectroscopy, FESEM, and High Resolution Transmission Electron Microscopy (HRTEM) analysis revealed the formation of amorphous carbon that could be responsible for its fast deactivation.