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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Krishnamurthy, Professor Satheesh
University of Surrey
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2024A comprehensive review on realization of self-cleaning surfaces by additive manufacturingcitations
- 2022Influence of Nanostructures in Perovskite Solar Cellscitations
- 2021Material dependent and temperature driven adsorption switching (p- to n- type) using CNT/ZnO composite-based chemiresistive methanol gas sensorcitations
- 2021Tin oxide for optoelectronic, photovoltaic and energy storage devices: a reviewcitations
- 2021Removal and Degradation of Mixed Dye Pollutants by Integrated Adsorption-Photocatalysis Technique Using 2-D MoS<sub>2</sub>/TiO<sub>2</sub> Nanocompositecitations
- 2020Solution Processed Pure Sulfide CZCTS Solar Cells with Efficiency 10.8% using Ultra-Thin CuO Intermediate Layercitations
- 2020Strength-ductility trade-off via SiC nanoparticle dispersion in A356 aluminium matrixcitations
- 2020Electro-deposited nano-webbed structures based on polyaniline/multi walled carbon nanotubes for enzymatic detection of organophosphatescitations
- 2019Continuous Hydrothermal Synthesis of Metal Germanates (M<sub>2</sub>GeO<sub>4</sub> ; M = Co, Mn, Zn) for High Capacity Negative Electrodes in Li‐ion Batteriescitations
- 2019Electrochemical micro analytical device interfaced with portable potentiostat for rapid detection of chlorpyrifos using acetylcholinesterase conjugated metal organic framework using Internet of thingscitations
- 2019Effects of Precursor Concentration in Solvent and Nanomaterials Room Temperature Aging on the Growth Morphology and Surface Characteristics of Ni–NiO Nanocatalysts Produced by Dendrites Combustion during SCScitations
- 2018Synthesis of MoS<sub>2</sub>-TiO<sub>2</sub> nanocomposite for enhanced photocatalytic and photoelectrochemical performance under visible light irradiationcitations
- 2017Tuning the properties of a black TiO<sub>2</sub>-Ag visible light photocatalyst produced by rapid one-pot chemical reductioncitations
- 2017Mediator-free interaction of glucose oxidase, as model enzyme for immobilization, with Al-doped and undoped ZnO thin films laser-deposited on polycarbonate supportscitations
- 2016Influence of Nanostructures in Perovskite Solar Cellscitations
- 2016Synthesis and characterisation of polyaniline (PAni) membranes for fuel cellcitations
- 2014Liquid phase pulsed laser ablation: a route to fabricate different carbon nanostructurescitations
- 2013Morphology-directed synthesis of ZnO nanostructures and their antibacterial activitycitations
- 2012Structural characterization of ZnO thin films grown on various substrates by pulsed laser depositioncitations
- 2011Resonant soft X-ray emission and X-ray absorption studies on Ga<sub>1-x</sub>Mn<sub>x</sub>N grown by pulsed laser depositioncitations
- 2010Transparent ultrathin conducting carbon filmscitations
- 2009Growth and characterisation of Al <sub>1-x</sub>Cr <sub>x</sub>N thin films by RF plasma assisted pulsed laser depositioncitations
- 2008High-yield production of graphene by liquid-phase exfoliation of graphitecitations
- 2008Growth of carbon nanotubes on Si substrate using Fe catalyst produced by pulsed laser deposition
Places of action
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article
Continuous Hydrothermal Synthesis of Metal Germanates (M<sub>2</sub>GeO<sub>4</sub> ; M = Co, Mn, Zn) for High Capacity Negative Electrodes in Li‐ion Batteries
Abstract
Nanosized metal germanates (M<sub>2</sub>GeO<sub>4</sub>; M = Co, Mn, Zn) were synthesised using a continuous hydrothermal flow synthesis process for the first time. Phase‐pure rhombohedral Zn<sub>2</sub>GeO<sub>4</sub> nanorods, cubic spinel Co<sub>2</sub>GeO<sub>4</sub> nanoparticles, and orthorhombic Mn2GeO4 nanotubes/nanoparticles were obtained. The electrochemical properties of all samples as active materials for negative electrodes in Li‐ion half cells was explored. The galvanostatic and potentiodynamic testing was conducted in the potential range 3.00 to 0.05 V vs. Li/Li<sup>+</sup>. The results suggest that both alloying and conversion reactions associated with Ge contributed to the stored charge capacity; Zn<sub>2</sub>GeO<sub>4</sub> showed a high specific capacity of 600 mAh g<sup>-1</sup> (10 cycles at 0.1 A g <sup>-1</sup>) due to alloying and conversion reactions for both Ge and Zn. Mn<sub>2</sub>GeO<sub>4</sub> was studied for the first time as a potential negative electrode material in a Li‐ion half‐cell; an excellent specific charge capacity of 510 mAh g<sup>-1</sup> (10 cycles / 0.1 A g<sup>-1</sup>) was obtained with a significant contribution to charge arising from the conversion reaction of Mn to MnO upon delithiation. In contrast, Co<sub>2</sub>GeO<sub>4</sub> only showed a specific capacity of 240 mAh g<sup>-1</sup>, after 10 cycles at the same current rate, which suggested that cobalt had little or no benefit for enhancing stored charge in the germanate.