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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gregory, Duncan
University of Glasgow
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2022Effects of iron substitution and anti-site disorder on crystal structures, vibrational, optical and magnetic properties of double perovskites Sr2(Fe1-xNix)TeO6citations
- 2022Effects of iron substitution and anti-site disorder on crystal structures, vibrational, optical and magnetic properties of double perovskites Sr<sub>2</sub>(Fe<sub>1−<i>x</i></sub>Ni<sub><i>x</i></sub>)TeO<sub>6</sub>citations
- 2020Highly efficient catalytic pyrolysis of polyethylene waste to derive fuel products by novel polyoxometalate/kaolin compositescitations
- 2020Facile in situ solution synthesis of SnSe/rGO nanocomposites with enhanced thermoelectric performancecitations
- 2020Towards new thermoelectrics : tin selenide/modified graphene oxide nanocompositescitations
- 2019Towards new thermoelectrics:tin selenide/modified graphene oxide nanocompositescitations
- 2019Towards new thermoelectricscitations
- 2017Ammonia borane-based nanocomposites as solid state hydrogen stores for portable power applicationscitations
- 2016Ba6−3xNd8+2xTi18O54 Tungsten Bronzecitations
Places of action
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article
Ammonia borane-based nanocomposites as solid state hydrogen stores for portable power applications
Abstract
Ammonia borane (AB) based nanocomposites have been investigated with the aim of developing a promising solid-state hydrogen store that complies with the requirements of a modular polymer electrolyte membrane fuel cell (PEM FC) in a portable power pack system. AB-carbon nanocomposites (prepared via ball milling or solution-impregnation) demonstrate improved hydrogen release performance compared to AB itself in terms of onset temperature and hydrogen purity, while maintaining a gravimetric density of more than 5 wt. % H2. The most promising of these materials is an AB-AC (activated carbon) composite, synthesised via solution-impregnation with an optimal dehydrogenation temperature of 96 °C. When combined with an external nickel chloride filter downstream, no evolved gaseous by-products can be detected above 100 ppb. The feasibility of an AB-AC storage tank has been further endorsed by simulations in which the reaction rate and the hydrogen flux was found to be almost constant as the temperature front propagated from the bottom to the top of the tank after initiation.