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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fritze, Holger
Clausthal University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Acoustic Loss in LiNb1−xTaxO3 at Temperatures up to 900 °C
- 2024Acoustic loss in LiNb1-xTaxO3 at temperatures up to 900 °C
- 2023Analysis of defect mechanisms in nonstoichiometric ceria–zirconia by the microwave cavity perturbation methodcitations
- 2023Chemical expansion of CeO2−δ and Ce0.8Zr0.2O2−δ thin films determined by laser Doppler vibrometry at high temperatures and different oxygen partial pressurescitations
- 2022Assembly and interconnection technology for high-temperature bulk acoustic wave resonatorscitations
- 2022In situ analysis of hydration and ionic conductivity of sulfonated poly(ether ether ketone) thin films using an interdigitated electrode array and a nanobalancecitations
- 2022Impact of electrode conductivity on mass sensitivity of piezoelectric resonators at high temperaturescitations
- 2021Linking the Electrical Conductivity and Non-Stoichiometry of Thin Film Ce1−xZrxO2−δ by a Resonant Nanobalance Approachcitations
- 2021Linking the electrical conductivity and non-stoichiometry of thin film Ce1−xZrxO2−δ by a resonant nanobalance approachcitations
- 2020High-temperature stable piezoelectric transducers using epitaxially grown electrodescitations
- 2020Determination of the Dielectric Properties of Storage Materials for Exhaust Gas Aftertreatment Using the Microwave Cavity Perturbation Methodcitations
- 2019Carbon pair defects in aluminum nitridecitations
- 2019Electromechanical losses in carbon- and oxygen-containing bulk AlN single crystals
- 2018Oxygen transport in epitaxial SrTiO3/SrTi1 − xFexO3 multilayer stackscitations
- 2018Thin-film nano-thermogravimetry applied to praseodymium-cerium oxide films at high temperaturescitations
- 2017Oxygen transport in epitaxial SrTiO3/SrTi1xFexO3 multilayer stackscitations
- 2017Oxygen transport in epitaxial SrTiO3/SrTi1 − xFexO3 multilayer stackscitations
- 2017Oxygen transport in epitaxial SrTiO3/SrTi1-xFexO3 multilayer stackscitations
- 2016Preparation and characterization of c-LiMn2O4 thin films prepared by pulsed laser deposition for lithium-ion batteriescitations
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article
Preparation and characterization of c-LiMn2O4 thin films prepared by pulsed laser deposition for lithium-ion batteries
Abstract
In this work, lithium manganese oxide (LMO) thin films are prepared using pulsed laser deposition (PLD) at room temperature. The as‐prepared films are amorphous and require a subsequent annealing step to achieve dense films of c‐spinel LMO (LiMn2O4). We applied different annealing temperatures under an argon atmosphere to investigate the thermodynamics of the films and to find the minimum crystallization temperature. Thereby, a simple film deposition process with only one subsequent annealing step is developed to prepare crystalline films. The samples are characterized using scanning electron microscopy (SEM), secondary ion mass spectrometry (SIMS), X‐ray diffraction (XRD), thin‐film‐calorimetry, impedance spectroscopy, and electrochemical methods. The results indicate that a narrow temperature range around 700 °C is suitable for the preparation of the spinel phase. Using this preparation route, no further crystalline phases could be identified by XRD. The electrochemical properties of the films are investigated and compared to electrodes made of commercially available LMO powders. The electrochemical characterization shows a capacity of 95 mAh g−1 for the commercial powder and 110 mAh g−1 for the thin‐film samples.