| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Quayle, Peter
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2019Synthesis and characterisation of fluorescent pyrene-end-capped polylactide fibrescitations
- 2019Low-temperature Pack Aluminization Process on Pipeline Steel to Inhibit Asphaltene Depositioncitations
- 2017The synthesis of group 10 and 11 metal complexes of 3,6,9-trithia- 1-(2,6)-pyridinacyclodecaphane and their use in A3-coupling reactionscitations
Places of action
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article
The synthesis of group 10 and 11 metal complexes of 3,6,9-trithia- 1-(2,6)-pyridinacyclodecaphane and their use in A3-coupling reactions
Abstract
The reaction between 3,6,9-trithia-1(2,6)-pyridinacyclodecaphane and representative group 10 and 11 metal salts [Cu(NO3)2, NiCl2 or Ag(CF3CO2 )] afforded 1:1 complexes which in the case of Cu(II) and Ag(I) were characterized by single crystal X-ray crystallography. The catalytic activity of these complexes in A3-coupling reactions between aldehydes, terminal alkynes and amines was assessed in both protic (water) and aprotic (toluene) media. These A3-reactions prove to be more efficient, proceed with lower catalyst loadings and with faster reaction rates, when conducted in a focused microwave reactor as compared to the same reactions promoted by standard, thermal, modes of activation