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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vitorica-Yrezabal, Inigo J.
Universidad de Granada
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups
- 2022Adsorption of sulphur dioxide in Cu(II)-carboxylate framework materials: the role of ligand functionalisation and open metal sites
- 2022Investigating the effect of steric hindrance within CdS single-source precursors on the material properties of AACVD and spin coat-deposited CdS thin filmscitations
- 2021Structural investigations of α-MnS nanocrystals and thin films synthesised from manganese(II) xanthates by hot injection, solvent-less thermolysis and doctor blade routes.citations
- 2020Single-Step Enantioselective Synthesis of Mechanically Planar Chiral [2]Rotaxanes Using a Chiral Leaving Group Strategycitations
- 2020Single-Step Enantioselective Synthesis of Mechanically Planar Chiral [2]Rotaxanes Using a Chiral Leaving Group Strategycitations
- 2019Synthesis of Iron Sulfide Thin Films and Powders from New Xanthate Precursorscitations
- 2019Chemical vapor deposition of tin sulfide from diorganotin(IV) dixanthatescitations
- 2019Accessing γ-Ga2S3 by solventless thermolysis of gallium xanthates: A low temperature limit for crystalline products?citations
- 2018Synthesis of Nanostructured Powders and Thin Films of Iron Sulfide from Molecular Precursorscitations
- 2018The synthesis of a monodisperse quaternary ferrite (FeCoCrO4) from the hot injection thermolysis of the single source precursor [CrCoFeO(O2C: TBu)6(HO2CtBu)3]citations
- 2017The synthesis of group 10 and 11 metal complexes of 3,6,9-trithia- 1-(2,6)-pyridinacyclodecaphane and their use in A3-coupling reactionscitations
- 2017Arene guest selectivity and pore flexibility in a metal–organic framework with semi-fluorinated channel wallscitations
- 2017Portraying entanglement between molecular qubits with four-dimensional inelastic neutron scatteringcitations
Places of action
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article
The synthesis of group 10 and 11 metal complexes of 3,6,9-trithia- 1-(2,6)-pyridinacyclodecaphane and their use in A3-coupling reactions
Abstract
The reaction between 3,6,9-trithia-1(2,6)-pyridinacyclodecaphane and representative group 10 and 11 metal salts [Cu(NO3)2, NiCl2 or Ag(CF3CO2 )] afforded 1:1 complexes which in the case of Cu(II) and Ag(I) were characterized by single crystal X-ray crystallography. The catalytic activity of these complexes in A3-coupling reactions between aldehydes, terminal alkynes and amines was assessed in both protic (water) and aprotic (toluene) media. These A3-reactions prove to be more efficient, proceed with lower catalyst loadings and with faster reaction rates, when conducted in a focused microwave reactor as compared to the same reactions promoted by standard, thermal, modes of activation