| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Vinu, Ajayan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Microwave Doping of Sulfur and Iron in β<sub>12</sub> Borophenecitations
- 2024Insights into Atomic Level π‐Electron Modulations in Supramolecular Carbon Nitride Nanoarchitectonics for Sustainable Green Hydrogen Productioncitations
- 2023Material-based generation, storage, and utilisation of hydrogencitations
- 2023Nuclearity Control in Molecular Copper Phosphates Derived from a Bulky Arylphosphate: Synthesis, Structural and Magnetic Studiescitations
- 2023Utilizing Nanozymatic Activity of Copper‐Functionlized Mesoporous C3N5 for Sensing of Biomoleculescitations
- 2022Rare‐Earth Doped Iron Oxide Nanostructures for Cancer Theranostics: Magnetic Hyperthermia and Magnetic Resonance Imagingcitations
- 2022Nanoporous materials for pesticide formulation and delivery in the agricultural sectorcitations
- 2019Freestanding Borophene and Its Hybridscitations
Places of action
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article
Nuclearity Control in Molecular Copper Phosphates Derived from a Bulky Arylphosphate: Synthesis, Structural and Magnetic Studies
Abstract
<jats:title>Abstract</jats:title><jats:p>Starting from sterically encumbered 2,6‐di‐<jats:italic>tert</jats:italic>‐butylphenyl phosphate (dtbppH<jats:sub>2</jats:sub>) and co‐ligand 3,5‐dimethyl pyrazole (dmpz), it is possible to isolate either mono‐, di‐ or tetranuclear copper phosphates by varying the copper source and making attendant changes in the reaction conditions. For example, reaction of copper nitrate with dtbppH<jats:sub>2</jats:sub> and dmpz at 60 °C leads to the isolation of the mononuclear copper phosphate [Cu(dtbppH)<jats:sub>2</jats:sub>(dmpz)(MeOH)<jats:sub>2</jats:sub>] (<jats:bold>1</jats:bold>) as the only product. However, the use of copper acetate in place of copper nitrate and conducting the reaction at the room temperature leads to the formation of both dinuclear [Cu(dtbpp)(dmpz)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub> (<jats:bold>2</jats:bold>) and tetranuclear [Cu<jats:sub>2</jats:sub>(dtbpp)(dmpz)<jats:sub>2</jats:sub>(OAc)(MeO)]<jats:sub>2</jats:sub> (<jats:bold>3</jats:bold>) from the same reaction mixture. Compounds <jats:bold>2</jats:bold> and <jats:bold>3</jats:bold> could be isolated in pure form through fractional crystallization. Copper phosphates <jats:bold>1</jats:bold>–<jats:bold>3</jats:bold> have been characterized by both analytical and spectroscopic methods including EPR and magnetic measurements. The molecular structures of all three compounds were established through single crystal diffraction studies. Dc magnetic measurements indicate antiferromagnetic interactions between the metal centres in all the compounds.</jats:p>