| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Guillemoles, Jean-François
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023The Role of Nonequilibrium LO Phonons, Pauli Exclusion, and Intervalley Pathways on the Relaxation of Hot Carriers in InGaAs Multi-Quantum-Well Structures
- 2023Breaking 1.7V open circuit voltage in large area transparent perovskite solar cells using bulk and interfaces passivation.citations
- 2023The modulated photoluminescence technique versus temperature: opportunities for better determination of trap parameters
- 2023The role of nonequilibrium LO phonons, Pauli exclusion, and intervalley pathways on the relaxation of hot carriers in InGaAs/InGaAsP multi-quantum-wellscitations
- 2022In – depth chemical and optoelectronic analysis of triple-cation perovskite thin films by combining XPS profiling and PL Imagingcitations
- 2021Mapping Transport Properties of Halide Perovskites via Short-Time-Dynamics Scaling Laws and Subnanosecond-Time-Resolution Imagingcitations
- 2021In – depth chemical and optoelectronic analysis of triple-cation perovskite thin films by combining XPS profiling and PL Imagingcitations
- 2021The influence of relative humidity upon Cu(In,Ga)Se2 thin-film surface chemistry: an X-ray photoelectron spectroscopy studycitations
- 2020Backside light management of 4-terminal bifacial perovskite/silicon tandem PV modules evaluated under realistic conditionscitations
- 2020Determination of photo-induced Seebeck coefficient for hot carrier solar cell applications
- 2019MIS Structures for Solar Cells Perimeter Passivation
- 2019Cu depletion on Cu(In,Ga)Se2 surfaces investigated by chemical engineering: An x-ray photoelectron spectroscopy approachcitations
- 2017Cathodoluminescence mapping for the determination of n-type doping in single GaAs nanowires
- 2017Tuning the chemical properties of europium complexes as downshifting agents for copper indium gallium selenide solar cellscitations
- 2017EuIII‐Based Nanolayers as Highly Efficient Downshifters for CIGS Solar Cellscitations
- 2014Monolithic Integration of Diluted-Nitride III–V-N Compounds on Silicon Substrates: Toward the III–V/Si Concentrated Photovoltaicscitations
- 2014Monolithic Integration of Diluted-Nitride III–V-N Compounds on Silicon Substrates: Toward the III–V/Si Concentrated Photovoltaicscitations
Places of action
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article
EuIII‐Based Nanolayers as Highly Efficient Downshifters for CIGS Solar Cells
Abstract
We report herein on the use of 13 ternary europium(III) complexes as downshifting (DS) material for copper indium gallium selenide (CIGS) solar cells. Their general formulae are [Eu(β‐Dik)3(NL)x] and [Eu(L)3], in which β‐Dik = 2‐thenoyltrifluoroacetonate, 4,4,4‐trifluoro‐1‐phenyl‐1,3‐butanedione and 4,4,4‐trifluoro‐1‐(2‐naphthyl)‐1,3‐butanedione and NL = diphenyl sulfoxide (x = 2), triphenylphosphine oxide (x = 2), bis[2‐(diphenylphosphino)phenyl] ether (x = 1), 5,6‐epoxy‐5,6‐dihydro‐1,10‐phenanthroline (x = 1) and 2‐(N,N‐diethylanilin‐4‐yl)‐4,6‐bis(3,5‐dimethylpyrazol‐1‐yl)‐1,3,5‐triazine (x = 1) and L = 4‐(4′‐tert‐butylbiphenyl‐4‐yl)‐2,2′‐bipyridine‐6‐carboxylate. Tris(β‐diketonate) ternary EuIII complexes are very good candidates for DS applications, and some of them have shown very promising results when embedded in a host organic polymer matrix typically used for solar cell encapsulations. Herein we report a new method for the direct deposition of luminescent nanolayer films on CIGS solar cells. Highly luminescent nano‐ and microlayer films with a thickness in the range of 150 nm to 10 µm have been obtained and characterized by optical microscopy, profilometry, spectrofluorimetry and external quantum efficiency (EQE) measurements. The efficient conversion of incident photons into red light was observed for films with a thickness of 400–600 nm, leading to a significant improvement in the EQE and short‐circuit current density (Jsc) in the UV region up to 0.81 mA/cm2. The absolute conversion efficiency increased by up to 0.8 %. The nanofilms, with the exception of those containing naphthyl derivatives, were found to be photostable and therefore represent a competitive alternative to doped polymer encapsulants.