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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Slaoui, Abdelilah
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Influence of Sodium Concentration on the Optoelectronic Properties of Silicon Clathrate Filmscitations
- 2023Tunability of silicon clathrate film properties by controlled guest-occupation of their cagescitations
- 2023Insights on CaTiS3 films grown by pulsed laser depositioncitations
- 2023Moderate temperature deposition of RF magnetron sputtered SnO2-based electron transporting layer for triple cation perovskite solar cellscitations
- 2022Nano-composite MOx materials for NVMscitations
- 2022Study of wide bandgap SnOx thin films grown by a reactive magnetron sputtering via a two-step methodcitations
- 2022Insights into Cu2O Thin Film Absorber via Pulsed Laser Depositioncitations
- 2020Growth and Characterization of (Tb,Yb) Co-Doping Sprayed ZnO Thin Filmscitations
- 2020Yb-doped zinc tin oxide thin film and its application to Cu(InGa)Se2 solar cellscitations
- 2019Cu(InGa)Se 2 Solar Cell Efficiency Enhancement Using a Yb-Doped SnO x Photon Converting Layercitations
- 2019EFFECT OF POTASSIUM CYANIDE ETCHING ON STRUCTURAL, OPTICAL AND ELECTRICAL PROPERTIES OF Cu2ZnSnS4 THIN FILMS DEPOSITED BY A MODIFIED SPRAY PROCESScitations
- 2018Tuning photovoltaic response in Bi 2 FeCrO 6 films by ferroelectric polingcitations
- 2017Tuning the chemical properties of europium complexes as downshifting agents for copper indium gallium selenide solar cellscitations
- 2017EuIII‐Based Nanolayers as Highly Efficient Downshifters for CIGS Solar Cellscitations
- 2017Polycrystalline silicon films obtained by crystallization of amorphous silicon on aluminium based substrates for photovoltaic applicationscitations
- 2011Effect of annealing treatments on photoluminescence and charge storage mechanism in silicon-rich SiNx:H films
- 2011Effect of ion implantation energy for the synthesis of Ge nanocrystals in SiN films with HfO2/SiO2stack tunnel dielectrics for memory application
- 2010Ultra-Low Energy Ion Implantation of Si into HfO2 and HfSiO-based Structures for Non Volatile Memory Applications
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article
EuIII‐Based Nanolayers as Highly Efficient Downshifters for CIGS Solar Cells
Abstract
We report herein on the use of 13 ternary europium(III) complexes as downshifting (DS) material for copper indium gallium selenide (CIGS) solar cells. Their general formulae are [Eu(β‐Dik)3(NL)x] and [Eu(L)3], in which β‐Dik = 2‐thenoyltrifluoroacetonate, 4,4,4‐trifluoro‐1‐phenyl‐1,3‐butanedione and 4,4,4‐trifluoro‐1‐(2‐naphthyl)‐1,3‐butanedione and NL = diphenyl sulfoxide (x = 2), triphenylphosphine oxide (x = 2), bis[2‐(diphenylphosphino)phenyl] ether (x = 1), 5,6‐epoxy‐5,6‐dihydro‐1,10‐phenanthroline (x = 1) and 2‐(N,N‐diethylanilin‐4‐yl)‐4,6‐bis(3,5‐dimethylpyrazol‐1‐yl)‐1,3,5‐triazine (x = 1) and L = 4‐(4′‐tert‐butylbiphenyl‐4‐yl)‐2,2′‐bipyridine‐6‐carboxylate. Tris(β‐diketonate) ternary EuIII complexes are very good candidates for DS applications, and some of them have shown very promising results when embedded in a host organic polymer matrix typically used for solar cell encapsulations. Herein we report a new method for the direct deposition of luminescent nanolayer films on CIGS solar cells. Highly luminescent nano‐ and microlayer films with a thickness in the range of 150 nm to 10 µm have been obtained and characterized by optical microscopy, profilometry, spectrofluorimetry and external quantum efficiency (EQE) measurements. The efficient conversion of incident photons into red light was observed for films with a thickness of 400–600 nm, leading to a significant improvement in the EQE and short‐circuit current density (Jsc) in the UV region up to 0.81 mA/cm2. The absolute conversion efficiency increased by up to 0.8 %. The nanofilms, with the exception of those containing naphthyl derivatives, were found to be photostable and therefore represent a competitive alternative to doped polymer encapsulants.