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Junk, P. C.
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Publications (6/6 displayed)
- 2017Synthesis and characterisation of heterobimetallic lanthanoid O-based cluster/cagescitations
- 2016Recent developments in environment-friendly corrosion inhibitors for mild steel
- 2007Structural versatility in hydrated rare earth(III) 1,2-benzenedisulfonatescitations
- 2006The Structural Systematics of Protonation of Some Important Nitrogen-base Lgands. III Some (Univalent) Anion Salts of some Hindered Unidentate Nitrogen Basescitations
- 2006The Structural Systematics of Protonation of Some Important Nitrogen-base Ligands. I Some Univalent Anion Salts of Doubly Protonated 2, 2′:6′, 2″-Terpyridylcitations
- 2004The trans-[py2AlCl4]- ('py' = pyridine) Anion, Structurally Characterized in Two Pyridinium Saltscitations
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article
Synthesis and characterisation of heterobimetallic lanthanoid O-based cluster/cages
Abstract
We report the syntheses of new mono- and bimetallic lanthanoid compounds. The metal ratio of tetra- and penta-nuclear clusters are determined by Energy Dispersive X-ray Spectroscopy (EDS). The results show, for an equal proportion of lanthanide salts introduced, different metal ratios are achieved for the clusters. This ratio appears to be dependent on the size and electronic density of the metals. Studies realized the best conditions to achieve a 1:1 metal ratio.