| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gorelik, Tatiana
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2020Orientational disorder of monomethyl-quinacridone investigated by Rietveld refinement, structure refinement to the pair distribution function and lattice-energy minimizationscitations
- 20193D Electron Diffraction: The Nanocrystallography Revolutioncitations
- 2019Towards quantitative treatment of electron pair distribution functioncitations
- 2015Structural insights into<i>M</i><sub>2</sub>O–Al<sub>2</sub>O<sub>3</sub>–WO<sub>3</sub>(<i>M</i>= Na, K) system by electron diffraction tomographycitations
- 2015Crystalline Non‐Equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligandscitations
- 2009Electron diffraction, X-ray powder diffraction and pair-distribution-function analyses to determine the crystal structures of Pigment Yellow 213, C<sub>23</sub>H<sub>21</sub>N<sub>5</sub>O<sub>9</sub>citations
- 2002Transmission electron microscopy study of Ge implanted into SiCcitations
- 2002Nanocrystal formation in SiC by Ge ion implantation and subsequent thermal annealingcitations
Places of action
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article
Crystalline Non‐Equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands
Abstract
<jats:title>Abstract</jats:title><jats:p>In six‐coordinate complexes, flexible tridentate ligands enable <jats:italic>mer</jats:italic>, <jats:italic>cis</jats:italic>‐<jats:italic>fac</jats:italic>, and <jats:italic>trans</jats:italic>‐<jats:italic>fac</jats:italic> stereoisomers. With labile metal ions of the first transition metal series, typically only the final thermodynamic product is available because of the rapid isomerization processes. Here we report on the structural characterization of a so far elusive kinetic intermediate of [Co(ddpd)<jats:sub>2</jats:sub>](BF<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>1</jats:bold>; ddpd = <jats:italic>N</jats:italic>,<jats:italic>N′</jats:italic>‐dimethyl‐<jats:italic>N</jats:italic>,<jats:italic>N′</jats:italic>‐dipyridine‐2‐yl‐pyridine‐2,6‐diamine). Microcrystals of the <jats:italic>cis</jats:italic>‐<jats:italic>fac</jats:italic> isomer of <jats:bold>1</jats:bold> were obtained by rapid precipitation. The solid‐state structure of <jats:bold><jats:italic>cis</jats:italic>‐<jats:italic>fac</jats:italic>‐1</jats:bold> was determined from electron diffraction data.</jats:p>