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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Heier, Jakob
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Integration of metal meshes as transparent conducting electrodes into perovskite solar cellscitations
- 2024Polypy: a framework to interpret polymer properties from mass spectroscopy datacitations
- 2024Polypy:A Framework to Interpret Polymer Properties from Mass Spectroscopy Datacitations
- 2024Polypy: A Framework to Interpret Polymer Properties from Mass Spectrometry Datacitations
- 2020Nanocellulose‐MXene biomimetic aerogels with orientation‐tunable electromagnetic interference shielding performancecitations
- 2018Cyanine platelet single crystals: growth, crystal structure and optical spectracitations
- 2015Influence of chemically p-type doped active organic semiconductor on the film thickness versus performance trend in cyanine/C60 bilayer solar cells
- 2015Influence of chemically p-type doped active organic semiconductor on the film thickness versus performance trend in cyanine/C 60 bilayer solar cellscitations
- 2014Photonic light trapping in self-organized all-oxide microspheroids impacts photoelectrochemical water splittingcitations
- 2012(Benzimidazolin-2-ylidene)-AuI-Alkynyl Complexescitations
- 2012Self-organised microdots formed by dewetting in a highly volatile liquidcitations
- 2011The effect of solvent and electric field on the size distribution of iron oxide microdots: exploitation of self-assembly strategies for photoelectrodescitations
- 2011Synthesis, thin-film morphology, and comparative study of bulk and bilayer heterojunction organic photovoltaic devices using soluble diketopyrrolopyrrole moleculescitations
- 2011Three dimensional analysis of self-structuring organic thin films using time-of-flight secondary ion mass spectrometrycitations
- 2010High performing doped cyanine bilayer solar cellcitations
- 2009Pattern formation in thin polymer films by spatially modulated electric fieldscitations
- 2009J-aggregation of cyanine dyes by self-assemblycitations
- 2007Interface control in organic heterojunction photovoltaic cells by phase separation processes
- 2007Interface morphology snapshots of vertically segregated thin films of semiconducting polymer/polystyrene blendscitations
- 2007Interface morphology snapshots of vertically segregated thin films of semiconducting polymer/polystyrene blendscitations
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article
(Benzimidazolin-2-ylidene)-AuI-Alkynyl Complexes
Abstract
<p>A series of N-heterocyclic carbene-based Au <sup>I</sup>-Ï-acetylide complexes of the type [(Bimz)Au-C⋯CR] (Bimz = benzimidazolin-2-ylidene; R = aryl, silyl groups) (1a-1l, 2, 3) were prepared from the precursor [(Bimz)Au <sup>I</sup>Cl] by an in situ deprotonation of the terminal alkynes. Steady-state photoluminescence studies revealed that most of these complexes exhibit phosphorescence at room temperature and in 77 K rigidified matrices. Molecular structures were determined by single-crystal X-ray diffraction studies for complexes 1a, 1b, 1e, 1f, 1h, 1k, and 1l. Complexes 1f, 1h, and 1l revealed weak unsupported aurophilic interactions. Cyclic voltammetry studies exhibited irreversible behavior with one oxidation peak potential (E <sub>p,a</sub>) for most cases in the region 0.7-1.4 V. Experimental and DFT studies suggest that the nature of the emission is predominantly of intraligand character <sup>3</sup>IL(π-π*) with a slight perturbation from the metal.</p>