| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Nieger, Martin
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2022A PH-functionalized dicationic bis(imidazolio)diphosphinecitations
- 2021Small Variations, Big Impact
- 2020A Ditopic Phosphane-decorated Benzenedithiol as Scaffold for Di- and Trinuclear Complexes of Group-10 Metals and Goldcitations
- 2019Synthesis of Functionalized Azobiphenyl‐ and Azoterphenyl‐ Ditopic Linkers: Modular Building Blocks for Photoresponsive Smart Materialscitations
- 2019Reactive intermediates in the reaction of hydrazinecarbothioamides with 2-(bis(methylthio)methylene)malononitrile and ethyl 2-cyano-3,3-bis(methylthio)acrylatecitations
- 2019A Ferrocenophane-Based Diaminophosphenium Ioncitations
- 2018Steric Control in Reactions of N-Heterocyclic Phosphorus Electrophiles with Pentacarbonyl Manganate(-I)citations
- 2017Polylutidinescitations
- 2017Polylutidines: Multifunctional Surfaces through Vapor-Based Polymerization of Substituted Pyridinophanescitations
- 2017Coordination of the ambiphilic phosphinoborane tBu(2)PCH(2)BPh(2) to Cu(I)Clcitations
- 2017Synthesis and Molecular Structures of Ferrocene and Zirconocene Featuring Bis(di(3,5-di-tert.-butyl)phenylphosphino) Groupscitations
- 2017N-Heterocyclic Phosphenium Dihalido-Auratescitations
- 2011Two- and three-dimensional packing diagrams of M(salophen) complexescitations
- 2009Template-controlled assembly of ditopic catechol phosphinescitations
- 2009Spontaneous phosphorus-halogen bond cleavage in N-heterocyclic halogenophosphanes revisitedcitations
- 2009Activation of polarized phosphorus-phosphorus bonds by alkynes
- 2008Pyrido-annellated diazaphospholenes and phospholenium ionscitations
- 2008A phosphanyl-substituted benzo-1,3,2-dioxaborol as ambiphilic bifunctional Lewis Donor-acceptor unitcitations
- 2007Boron templated catechol phosphines as bidentate ligands in silver complexescitations
- 20072-Chloro-1,3,2-diazaphospholenes - a crystal structural studycitations
- 2005Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinatescitations
Places of action
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article
A phosphanyl-substituted benzo-1,3,2-dioxaborol as ambiphilic bifunctional Lewis Donor-acceptor unit
Abstract
"Condensation of 3-[(diphenylphosphanyl)methyl]benzene-1,2-diol (1) with phenyl boronic acid gave a phosphane-functionalised benzo-1,3,2-dioxaborol 3. The ability of this species to act as a Lewis base through the P-centered donor and as a Lewis acid through the B-centered acceptor sites was demonstrated by the reactions with (cod)PdCl2 and some nitrogen donors (4-dimethylaminopyridine, diaza-[2.2.2]-bicyclooctane, pyridine). These reactions yielded either palladium-phosphane complexes or amine-borane adducts that were characterised by spectroscopic data and, in some cases, by single-crystal X-ray diffraction studies. Reactions of a Pd complex of the phosphane-functionalised benzo-1,3,2-dioxaborol 3 with dabco, or of the dmap adduct of 3 with (cod)PdCl2, gave materials that were characterised by analytical data and solid-state NMR spectroscopic data as triple Lewis acid/base complexes and that contain both P -> Pd and B <- N dative bonds. Even though these adducts were unstable in solution, the results of these experiments demonstrate the ability of 3 to act as a bifunctional donor/acceptor ligand, which is of potential use as a building block for main chain organometallic polymers or multimetallic complexes. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)."