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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nieger, Martin
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2022A PH-functionalized dicationic bis(imidazolio)diphosphinecitations
- 2021Small Variations, Big Impact
- 2020A Ditopic Phosphane-decorated Benzenedithiol as Scaffold for Di- and Trinuclear Complexes of Group-10 Metals and Goldcitations
- 2019Synthesis of Functionalized Azobiphenyl‐ and Azoterphenyl‐ Ditopic Linkers: Modular Building Blocks for Photoresponsive Smart Materialscitations
- 2019Reactive intermediates in the reaction of hydrazinecarbothioamides with 2-(bis(methylthio)methylene)malononitrile and ethyl 2-cyano-3,3-bis(methylthio)acrylatecitations
- 2019A Ferrocenophane-Based Diaminophosphenium Ioncitations
- 2018Steric Control in Reactions of N-Heterocyclic Phosphorus Electrophiles with Pentacarbonyl Manganate(-I)citations
- 2017Polylutidinescitations
- 2017Polylutidines: Multifunctional Surfaces through Vapor-Based Polymerization of Substituted Pyridinophanescitations
- 2017Coordination of the ambiphilic phosphinoborane tBu(2)PCH(2)BPh(2) to Cu(I)Clcitations
- 2017Synthesis and Molecular Structures of Ferrocene and Zirconocene Featuring Bis(di(3,5-di-tert.-butyl)phenylphosphino) Groupscitations
- 2017N-Heterocyclic Phosphenium Dihalido-Auratescitations
- 2011Two- and three-dimensional packing diagrams of M(salophen) complexescitations
- 2009Template-controlled assembly of ditopic catechol phosphinescitations
- 2009Spontaneous phosphorus-halogen bond cleavage in N-heterocyclic halogenophosphanes revisitedcitations
- 2009Activation of polarized phosphorus-phosphorus bonds by alkynes
- 2008Pyrido-annellated diazaphospholenes and phospholenium ionscitations
- 2008A phosphanyl-substituted benzo-1,3,2-dioxaborol as ambiphilic bifunctional Lewis Donor-acceptor unitcitations
- 2007Boron templated catechol phosphines as bidentate ligands in silver complexescitations
- 20072-Chloro-1,3,2-diazaphospholenes - a crystal structural studycitations
- 2005Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinatescitations
Places of action
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article
2-Chloro-1,3,2-diazaphospholenes - a crystal structural study
Abstract
"A series of 2-chloro-1,3,2-diazaphospholenes with different substitution patterns has been prepared from 1,4-diazabutadienes according to a general synthetic methodology. Subsequent chloride abstraction with Lewis acids affords the corresponding 1,3,2-diazaphospholenium salts. All products have been characterised spectroscopically and by single-crystal X-ray diffraction studies. A detailed analysis of trends in the structural parameters supports the interpretation that the unusual P-Cl bond lengthening in the diazaphospholenes is attributable to n(N)/sigma*(P-Cl) hyperconjugation. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)."