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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lewiński, Janusz
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Unprecedented Richness of Temperature‐ and Pressure‐Induced Polymorphism in 1D Lead Iodide Perovskitecitations
- 2024High‐Performance Perovskite Solar Cells with Zwitterion‐Capped‐ZnO Quantum Dots as Electron Transport Layer and <scp>NH<sub>4</sub></scp>X (X = F, Cl, Br) Assisted Interfacial Engineeringcitations
- 2023A modular design approach to polymer-coated ZnO nanocrystals
- 2021From Uncommon Ethylzinc Complexes Supported by Ureate Ligands to Water-Soluble ZnO Nanocrystals: A Mechanochemical Approachcitations
- 2021Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxidescitations
- 2021ZnO Nanoplatelets with Controlled Thickness: Atomic Insight into Facet‐Specific Bimodal Ligand Binding Using DNP NMRcitations
- 2020Interpretation of Resistance, Capacitance, Defect Density, and Activation Energy Levels in Single-Crystalline MAPbI3citations
- 2016Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane unitscitations
- 2014A New Look at the Reactivity of TEMPO towards Diethylzinccitations
- 2014A solvothermal and mechanochemical strategy for the construction of chiral N,N-ditopic metalloligands: Oxygenation process of a Cu(I)X/Quinine systemcitations
- 2012Synthesis, Structure and Unique Reactivity of the Ethylzinc Derivative of a Bicyclic Guanidinecitations
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article
High‐Performance Perovskite Solar Cells with Zwitterion‐Capped‐ZnO Quantum Dots as Electron Transport Layer and <scp>NH<sub>4</sub></scp>X (X = F, Cl, Br) Assisted Interfacial Engineering
Abstract
<jats:p>The systematic advances in the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs) have been driven by the developments of perovskite materials, electron transport layer (ETL) materials, and interfacial passivation between the relevant layers. While zinc oxide (ZnO) is a promising ETL in thin film photovoltaics, it is still highly desirable to develop novel synthetic methods that allow both fine‐tuning the versatility of ZnO nanomaterials and improving the ZnO/perovskite interface. Among various inorganic and organic additives, zwitterions have been effectively utilized to passivate the perovskite films. In this vein, we develop novel, well‐characterized betaine‐coated ZnO QDs and use them as an ETL in the planar n‐i‐p PSC architecture, combining the ZnO QDs‐based ETL with the ZnO/perovskite interface passivation by a series of ammonium halides (NH<jats:sub>4</jats:sub>X, where X = F, Cl, Br). The champion device with the NH<jats:sub>4</jats:sub>F passivation achieves one of the highest performances reported for ZnO‐based PSCs, exhibiting a maximum PCE of ~22% with a high fill factor of 80.3% and competitive stability, retaining ~78% of its initial PCE under 1 Sun illumination with maximum power tracking for 250 h.</jats:p>