| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Dong, Renhao
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Coexistence of Redox‐Active Metal and Ligand Sites in Copper‐based 2D Conjugated Metal‐Organic Frameworks for Battery‐Supercapacitor hybrid systemscitations
- 2023Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Filmcitations
- 2023On-water surface synthesis of electronically coupled 2D polyimide-MoS2 van der Waals heterostructurecitations
- 2023Tunable Crystallinity and Electron Conduction in Wavy 2D Conjugated Metal–Organic Frameworks via Halogen Substitutioncitations
- 2023Near IR Bandgap Semiconducting 2D Conjugated Metal‐Organic Framework with Rhombic Lattice and High Mobilitycitations
- 2021Multiscale Modeling Strategy of 2D Covalent Organic Frameworks Confined at an Air–Water Interfacecitations
- 2020Near–atomic-scale observation ofgrain boundaries inalayer-stacked two-dimensional polymercitations
- 2020Two-Dimensional Boronate Ester Covalent Organic Framework Thin Films with Large Single Crystalline Domains for a Neuromorphic Memory Devicecitations
- 2020Highly crystalline and semiconducting imine‐based two‐dimensional polymers enabled by interfacial synthesis
- 2019Engineering crystalline quasi-two-dimensional polyaniline thin film with enhanced electrical and chemiresistive sensing performancescitations
- 2017Persulfurated Coronene: A New Generation of "Sulflower"citations
- 2017Coordination Polymer Framework Based On-Chip Micro-Supercapacitors with AC Line-Filtering Performancecitations
Places of action
| Organizations | Location | People |
|---|
article
Coexistence of Redox‐Active Metal and Ligand Sites in Copper‐based 2D Conjugated Metal‐Organic Frameworks for Battery‐Supercapacitor hybrid systems
Abstract
<jats:p>Two‐dimensional (2D) conjugated metal‐organic frameworks (c‐MOFs) are promising materials for supercapacitor (SC) electrodes due to their high electrochemically accessible surface area coupled with superior electrical conductivity compared to traditional MOFs. Here, porous and non‐porous HHB‐Cu (HHB=hexahydroxybenzene), derived through surfactant‐assisted synthesis, are studied as representative 2D c‐MOF models, showing different reversible redox reactions with Na+ and Li+ in aqueous and organic electrolytes, respectively. We deployed these redox activities to design negative electrodes for hybrid SCs (HSCs), combining the battery‐like property of HHB‐Cu as negative electrode and the high capacitance and robust cyclic stability of activated carbon (AC) as positive electrode. In organic electrolyte, porous HHB‐Cu‐based HSC achieves a maximum cell specific capacity (Cs) of 22.1 mAhg‐1 at 0.1 Ag‐1, specific energy (Es) of 15.55 Whkg‐1 at specific power (Ps) of 70.49 Wkg‐1, and 77% cyclic stability after 3000 gravimetric charge‐discharge (GCD) cycles at 1 Ag‐1 (calculated on the mass of both electrode materials). In the aqueous electrolyte, porous HHB‐Cu‐based HSC displays a Cs of 13.9 mAhg‐1 at 0.1 Ag‐1, Es of 6.13 Whkg‐1 at 44.05 Wkg‐1, and 72.3% Cs retention after 3000 GCD cycles. The non‐porous sample shows lower Es performance but better rate capability compared to the porous one.</jats:p>