| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Oezaslan, Mehtap
Technische Universität Braunschweig
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Monitoring the Morphological Changes of Skeleton-PtCo Electrocatalyst during PEMFC Start-Up/Shut-Downprobed by in situ WAXS and SAXScitations
- 2024Monitoring the Morphological Changes of Skeleton-PtCo Electrocatalyst during PEMFC Start-Up/Shut-Down probed by in situ WAXS and SAXS.citations
- 2024Tuning the morphology and chemical distribution of Ag atoms in Au rich nanoparticles using electrochemical dealloyingcitations
- 2023Chemical Insights into the Formation of Colloidal Iridium Nanoparticles from In Situ X-ray Total Scatteringcitations
- 2023Nanoporous Gold: From Structure Evolution to Functional Properties in Catalysis and Electrochemistry
- 2023Chemical Insights into the Formation of Colloidal Iridium Nanoparticles from In Situ X-ray Total Scattering:Influence of Precursors and Cations on the Reaction Pathwaycitations
- 2023Chemical Insights into the Formation of Colloidal Iridium Nanoparticles from In Situ X-ray Total Scattering:Influence of Precursors and Cations on the Reaction Pathwaycitations
- 2022Highly Durable Pt-Based Core-Shell Catalysts with Metallic and Oxidized Cobalt Species for Boosting the Oxygen Reduction Reaction
- 2022Nanoporous Copper Ribbons Prepared by Chemical Dealloying of a Melt-Spun ZnCu Alloycitations
- 2020Solvent-dependent growth and stabilization mechanisms of surfactant-free colloidal Pt nanoparticlescitations
- 2020Solvent-dependent growth and stabilization mechanisms of surfactant-free colloidal Pt nanoparticlescitations
- 2020The Dissolution Dilemma for Low Pt Loading Polymer Electrolyte Membrane Fuel Cell Catalystscitations
- 2018Structural Analysis and Electrochemical Properties of Bimetallic Palladium–Platinum Aerogels Prepared by a Two‐Step Gelation Processcitations
- 2018Solutions for catalysis: A surfactant-free synthesis of precious metal nanoparticle colloids in mono-alcohols for catalysts with enhanced performances
- 2017Durabilty of Pt-Based Alloy Nanoparticles Supported on Functionalized Carbon Materials for the ORR – Tuning the Interaction between Particles and Support Material
- 2015Noble Metal Aerogels - Synthesis, Characterization, and Application as Electrocatalysts
Places of action
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article
Monitoring the Morphological Changes of Skeleton-PtCo Electrocatalyst during PEMFC Start-Up/Shut-Downprobed by in situ WAXS and SAXS
Abstract
Advanced in situ analyses are indispensable for comprehending the catalyst aging mechanisms of Pt-based PEM fuel cell cathode materials, particularly during accelerated stress tests (ASTs). In this study, a combination of in situ small-angle and wide-angle X-ray scattering (SAXS & WAXS) techniques were employed to establish correlations between structural parameters (crystal phase, quantity, and size) of a highly active skeleton-PtCo (sk-PtCo) catalyst and their degradation cycles within the potential range of the start-up/shut-down (SUSD) conditions. Despite the complex case of the sk-PtCo catalyst comprising two distinct fcc alloy phases, our complementary techniques enabled in situ monitoring of structural changes in each crystal phase in detail. Remarkably, the in situ WAXS measurements uncover two primary catalyst aging processes, namely the cobalt depletion (regime I) followed by the crystallite growth via Ostwald ripening and/or particle coalescence (regime II). Additionally, in situ SAXS data reveal a continuous size growth over the AST. The Pt-enriched shell thickening based on the Co depletion within the first 100 SUSD cycles and particle growth induced by additional potential cycles were also collaborated by ex situ STEM-EELS. Overall, our work shows a comprehensive aging model for the sk-PtCo catalyst probed by complementary in situ WAXS and SAXS techniques.