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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Veziroglu, Salih
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024ITO-TiO2 Heterojunctions on Glass Substrates for Photocatalytic Gold Growth Along Pattern Edges
- 2024Self‐Modification of Defective TiO<sub>2</sub> under Controlled H<sub>2</sub>/Ar Gas Environment and Dynamics of Photoinduced Surface Oxygen Vacanciescitations
- 2024Antibacterial properties of marine algae incorporated polylactide acid membranes as an alternative to clinically applied different collagen membranescitations
- 2021Tuning wettability of TiO 2 thin film by photocatalytic deposition of 3D flower- and hedgehog-like Au nano- and microstructurescitations
- 2021Selective Laser Melting of 316L Austenitic Stainless Steel: Detailed Process Understanding Using Multiphysics Simulation and Experimentationcitations
- 2021Initiated chemical vapor deposition (Icvd) functionalized polylactic acid–marine algae composite patch for bone tissue engineeringcitations
- 2021Initiated chemical vapor deposition (Icvd) functionalized polylactic acid–marine algae composite patch for bone tissue engineeringcitations
- 2021Tuning wettability of TiO2 thin film by photocatalytic deposition of 3D flower- and hedgehog-like Au nano- and microstructurescitations
- 2021Marine algae incorporated polylactide acid patchcitations
- 2021Selective laser melting of 316L austenitic stainless steel:detailed process understanding using multiphysics simulation and experimentationcitations
- 2019Pathways to Tailor Photocatalytic Performance of TiO2 Thin Films Deposited by Reactive Magnetron Sputteringcitations
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article
Self‐Modification of Defective TiO<sub>2</sub> under Controlled H<sub>2</sub>/Ar Gas Environment and Dynamics of Photoinduced Surface Oxygen Vacancies
Abstract
<jats:title>Abstract</jats:title><jats:p>In recent years, defective TiO<jats:sub>2</jats:sub> has caught considerable research attention because of its potential to overcome the limits of low visible light absorption and fast charge recombination present in pristine TiO<jats:sub>2</jats:sub> photocatalysts. Among the different synthesis conditions for defective TiO<jats:sub>2</jats:sub>, ambient pressure hydrogenation with the addition of Ar as inert gas for safety purposes has been established as an easy method to realize the process. Whether the Ar gas might still influence the resulting photocatalytic properties and defective surface layer remains an open question. Here, we reveal that the gas flow ratio between H<jats:sub>2</jats:sub> and Ar has a crucial impact on the defective structure as well as the photocatalyic activity of TiO<jats:sub>2</jats:sub>. In particular, transmission electron microscopy (TEM) in combination with electron energy loss spectroscopy (EELS) revealed a larger width of the defective surface layer when using a H<jats:sub>2</jats:sub>/Ar (50 %–50 %) gas mixture over pure H<jats:sub>2</jats:sub>. A possible reason could be the increase in dynamic viscosity of the gas mixture when Ar is added. Additionally, photoinduced enhanced Raman spectroscopy (PIERS) is implemented as a complementary approach to investigate the dynamics of the defective structures under ambient conditions which cannot be effortlessly realized by vacuum techniques like TEM.</jats:p>