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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dsoke, Sonia
University of Freiburg
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Modification of AI surface via acidic treatment and its impact on plating and strippingcitations
- 2024Modification of Al Surface via Acidic Treatment and its Impact on Plating and Strippingcitations
- 2024Hindered Aluminum Plating and Stripping in Urea/NMA/Al(OTF)$_3$ as a Cl-Free Electrolyte for Aluminum Batteries
- 2024Side-reactions of polyvinylidene fluoride and polyvinylidene chloride binders with aluminum chloride-based ionic liquid electrolyte in rechargeable aluminum-batteriescitations
- 2023From high‐pressure $β‐V_2O_5$ to $κ‐Na_xV_2O_5$ ( x = 0.4 − 0.55): A structural, chemical, and kinetic insight into a sodiated phase with a large interlayer spacecitations
- 2023Modification of Al Surface via Acidic Treatment and its Impact on Plating and Stripping
- 2023Surface Properties‐Performance Relationship of Aluminum Foil as Negative Electrode for Rechargeable Aluminum Batteriescitations
- 2020Choosing the right carbon additive is of vital importance for high-performance Sb-based Na-ion batteriescitations
- 2020Probing the Effect of Titanium Substitution on the Sodium Storage in Na₃Ni₂BiO₆ Honeycomb-Type Structurecitations
- 2020Effect of Continuous Capacity Rising Performed by FeS/Fe₃C/C Composite Electrodes for Lithium‐Ion Batteriescitations
- 2020Effect of continuous capacity rising performed by FeS/Fe3C/C composite electrodes for lithium‐ion batteriescitations
- 2019Understanding the Lithium Storage Mechanism in Core–Shell $Fe_{2}O_{3}@C$ Hollow Nanospheres Derived from Metal–Organic Frameworks: An In operando Synchrotron Radiation Diffraction and in operando X-ray Absorption Spectroscopy Studycitations
- 2019Evidence of a Pseudo-Capacitive Behavior Combined with an Insertion/Extraction Reaction Upon Cycling of the Positive Electrode Material $mathrm{P2-Na_{x}Co_{0.9}Ti_{0.1}O_{2}}$ for Sodium-ion Batteriescitations
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article
Effect of Continuous Capacity Rising Performed by FeS/Fe₃C/C Composite Electrodes for Lithium‐Ion Batteries
Abstract
FeS‐based composites are sustainable conversion electrode materials for lithium‐ion batteries, combining features like low cost, environmental friendliness, and high capacities. However, they suffer from fast capacity decay and low electron conductivity. Herein, novel insights into a surprising phenomenon of this material are provided. A FeS/Fe3C/C nanocomposite synthesized by a facile hydrothermal method is compared with pure FeS. When applied as anode materials for lithium‐ion batteries, these two types of materials show different capacity evolution upon cycling. Surprisingly, the composite delivers a continuous increase in capacity instead of the expected capacity fading. This unique behavior is triggered by a catalyzing effect of Fe3C nanoparticles. The Fe3C phase is a beneficial byproduct of the synthesis and was not intentionally obtained. To further understand the effect of interconnected carbon balls on FeS‐based electrodes, complementary analytic techniques are used. Ex situ X‐ray radiation diffraction and ex situ scanning electron microscopy are employed to track phase fraction and morphology structure. In addition, the electrochemical kinetics and resistance are evaluated by cyclic voltammetry and electrochemical impedance spectroscopy. These results reveal that the interconnected carbon balls have a profound influence on the properties of FeS‐based electrodes resulting in an increased electrode conductivity, reduced particle size, and maintenance of the structure integrity.