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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Genç, Aziz
Cardiff University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Asymmetrical Plasmon Distribution in Hybrid AuAg Hollow/Solid Coded Nanotubescitations
- 2022Recyclability of CsPbBr<sub>3</sub> quantum dot glass nanocomposites for their long-standing use in white LEDscitations
- 2021Exploiting the lability of metal halide perovskites for doping semiconductor nanocompositescitations
- 2019Ligand-mediated band engineering in bottom-up assembled SnTe nanocomposites for thermoelectric energy conversioncitations
- 2019Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blockscitations
- 2019Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blockscitations
- 2019Hollow PdAg-CeO2 heterodimer nanocrystals as highly structured heterogeneous catalystscitations
- 2017Polybenzoxazine‐Derived N‐doped Carbon as Matrix for Powder‐Based Electrocatalystscitations
- 2016Polymer-enhanced stability of inorganic perovskite nanocrystals and their application in color conversion LEDscitations
- 2016High-performance thermoelectric nanocomposites from nanocrystal building blockscitations
Places of action
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article
Polybenzoxazine‐Derived N‐doped Carbon as Matrix for Powder‐Based Electrocatalysts
Abstract
<jats:title>Abstract</jats:title><jats:p>In addition to catalytic activity, intrinsic stability, tight immobilization on a suitable electrode surface, and sufficient electronic conductivity are fundamental prerequisites for the long‐term operation of particle‐ and especially powder‐based electrocatalysts. We present a novel approach to concurrently address these challenges by using the unique properties of polybenzoxazine (pBO) polymers, namely near‐zero shrinkage and high residual‐char yield even after pyrolysis at high temperatures. Pyrolysis of a nanocubic prussian blue analogue precursor (K<jats:sub><jats:italic>m</jats:italic></jats:sub>Mn<jats:sub><jats:italic>x</jats:italic></jats:sub>[Co(CN)<jats:sub>6</jats:sub>]<jats:sub><jats:italic>y</jats:italic></jats:sub>⋅<jats:italic>n</jats:italic> H<jats:sub>2</jats:sub>O) embedded in a bisphenol A and aniline‐based pBO led to the formation of a N‐doped carbon matrix modified with Mn<jats:sub><jats:italic>x</jats:italic></jats:sub>Co<jats:sub><jats:italic>y</jats:italic></jats:sub>O<jats:sub><jats:italic>z</jats:italic></jats:sub> nanocubes. The obtained electrocatalyst exhibits high efficiency toward the oxygen evolution reaction (OER) and more importantly a stable performance for at least 65 h.</jats:p>