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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hey-Hawkins, Evamarie
Leipzig University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2023Molybdenum‐Mediated Insertion of Ketones into the P−P bond of <i>cyclo</i>‐(P<sub>5</sub>Ph<sub>5</sub>) and Formation of Trinuclear Molybdenum Complexescitations
- 2022New Boron Delivery Agents
- 2020Ruthenacarborane–Phenanthroline Derivatives as Potential Metallodrugs
- 2019Selective Laser Sintering of Metal-Organic Frameworks : Production of Highly Porous Filters by 3D Printing onto a Polymeric Matrixcitations
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article
Molybdenum‐Mediated Insertion of Ketones into the P−P bond of <i>cyclo</i>‐(P<sub>5</sub>Ph<sub>5</sub>) and Formation of Trinuclear Molybdenum Complexes
Abstract
<jats:title>Abstract</jats:title><jats:p>The reaction of cyclopentaphosphine <jats:italic>cyclo</jats:italic>‐(P<jats:sub>5</jats:sub>Ph<jats:sub>5</jats:sub>) (<jats:bold>1</jats:bold>) with ketones (acetone and cyclooctanone) in the presence of [Mo(CO)<jats:sub>4</jats:sub>(cod)] (cod=cycloocta‐1,5‐diene) led to air‐stable trinuclear complexes in which the bis‐phosphanido ligands (PPh−PPh−PPh−PPh−CMe<jats:sub>2</jats:sub>O−PPh)<jats:sup>2−</jats:sup> (complex <jats:bold>2</jats:bold>) and (PPh−PPh−PPh−PPh−C(CH<jats:sub>2</jats:sub>)<jats:sub>7</jats:sub>O−PPh)<jats:sup>2−</jats:sup> (complex <jats:bold>3</jats:bold>) bridge a Mo(CO)<jats:sub>3</jats:sub>−Mo(CO)<jats:sub>3</jats:sub> unit. This extends the reaction of <jats:bold>1</jats:bold> with transition metal carbonyl complexes to further substrates and represents the first examples of insertion of carbonyl compounds into the P−P bond of cyclic oligophosphorus compounds. Complexes <jats:bold>2</jats:bold> and <jats:bold>3</jats:bold> have been characterized by <jats:sup>31</jats:sup>P NMR spectroscopy and single crystal X‐ray diffraction. Furthermore, the thermal properties of the obtained complexes have been studied by differential scanning calorimetry (DSC) and fast scanning calorimetry (FSC).</jats:p>