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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Xiao, Xinxin
Aalborg University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Understanding molecular and electrochemical charge transfer: theory and computationscitations
- 2019Three-Dimensional Sulfite Oxidase Bioanodes Based on Graphene Functionalized Carbon Paper for Sulfite/O2 Biofuel Cellscitations
- 2019Three-Dimensional Sulfite Oxidase Bioanodes Based on Graphene Functionalized Carbon Paper for Sulfite/O2 Biofuel Cellscitations
- 2019Use of Polymer Coatings to Enhance the Response of Redox-Polymer-Mediated Electrodescitations
- 2019Three-dimensional bioelectrodes utilizing graphene based bioinkcitations
- 2019Three-dimensional sulfite oxidase bioanodes based on graphene functionalized carbon paper for sulfite/O-2 biofuel cellscitations
- 2017A symmetric supercapacitor/biofuel cell hybrid device based on enzyme-modified nanoporous gold:An autonomous pulse generatorcitations
- 2017Immobilization of Redox Enzymes on Nanoporous Gold Electrodes: Applications in Biofuel Cellscitations
- 2017A symmetric supercapacitor/biofuel cell hybrid device based on enzyme-modified nanoporous goldcitations
- 2017Immobilization of Redox Enzymes on Nanoporous Gold Electrodescitations
- 2016Nanoporous Gold Electrodes with Tuneable Pore Sizes for Bioelectrochemical Applicationscitations
Places of action
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article
Immobilization of Redox Enzymes on Nanoporous Gold Electrodes
Abstract
<p>Nanoporous gold (NPG) electrodes were prepared by dealloying sputtered gold:silver alloys. Electrodes of different thicknesses and pore sizes areas were prepared by varying the temperature and duration of the dealloying procedure; these were then used as supports for FAD-dependent glucose dehydrogenase (GDH) (Glomorella cingulata) and bilirubin oxidase (BOx) (Myrothecium verrucaria). Glucose dehydrogenase was immobilized by drop-casting a solution of the enzyme with an osmium redox polymer together with a crosslinked polymer, whereas bilirubin oxidase was attached covalently through carbodiimide coupling to a diazonium-modified NPG electrode. The stability of the bilirubin-oxidase-modified NPG electrode was significantly improved in comparison with that of a planar gold electrode. Enzyme fuel cells were also prepared; the optimal response was obtained with a BOx-modified NPG cathode (500 nm thickness) and a GDH-modified anode (300 nm), which generated power densities of 17.5 and 7.0 μW cm<sup>−2</sup> in phosphate-buffered saline and artificial serum, respectively.</p>