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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hall, David
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2025Investigation of electric field-induced phase transitions in unfilled tungsten bronze relaxor ceramics designed by the high entropy conceptcitations
- 2024In situ electric field-dependent structural changes in (Ba,Ca)(Zr,Ti)O 3 with varying grain sizecitations
- 2024Temperature-Dependent Ferroelectric Properties and Aging Behavior of Freeze-Cast Bismuth Ferrite-Barium Titanate Ceramicscitations
- 2024Broadband dielectric spectroscopy of Nb-doped 0.7BiFeO 3 -0.3BaTiO 3 ceramics
- 2024Temperature-Dependent Ferroelectric Properties and Aging Behavior of Freeze-Cast Bismuth Ferrite–Barium Titanate Ceramicscitations
- 2024Influence of Grain Size on Electromechanical Properties of (Ba,Ca)(Zr,Ti)O 3 : A Multiscale Analysis Using Spark Plasma Sintering and Aerosol Depositioncitations
- 2024Organic Light-Emitting Diodes Comprising an Undoped Thermally Activated Delayed Fluorescence Emissive Layer and a Thick Inorganic Perovskite Hole Transport Layer
- 2024Domain switching and shear-mode piezoelectric response induced by cross-poling in polycrystalline ferroelectricscitations
- 2023Re-entrant Relaxor Ferroelectric Behaviour in Nb-Doped BiFeO3-BaTiO3 Ceramicscitations
- 2022Residual stress and domain switching in freeze cast porous barium titanatecitations
- 2020Reducing the Athena WFI charged particle background: results from Geant4 simulationscitations
- 2018Influence of K 0.5 Bi 0.5 TiO 3 on the structure, dielectric and ferroelectric properties of (Ba,Ca)(Zr,Ti)O 3 ceramicscitations
- 2018Optimisation of functional properties in lead-free BiFeO 3 –BaTiO 3 ceramics through La 3+ substitution strategycitations
- 2017Chemical heterogeneity and approaches to its control in BiFeO 3 - BaTiO 3 lead-free ferroelectricscitations
- 2015Revisiting the blocking force test on ferroelectric ceramics using high energy x-ray diffractioncitations
- 2015The development of Zn–Ce hybrid redox flow batteries for energy storage and their continuing challengescitations
- 2014Development of EM-CCD-based X-ray detector for synchrotron applicationscitations
Places of action
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article
The development of Zn–Ce hybrid redox flow batteries for energy storage and their continuing challenges
Abstract
The Zn–Ce flow battery is a recently introduced hybrid redox flow battery (RFB) but has been extensively studied in the laboratory and at the industrial pilot scale since its introduction in 2005. The cell has the highest open-circuit cell potentials amongst aqueous RFBs, which can exceed 2.4 V at full charge. Although original patents were filed in 2004 and 2005, the history of the half-cell reactions stretches back many decades, with the Ce(IV)/Ce(III) redox couple being well studied in sulphuric acid as a redox mediator in organic electrosynthesis or in nitric acid for specialist cleaning in the chemical and nuclear industries; in addition, zinc deposition and stripping in acid media are well known in hydrometallurgy and electroplating of metals as well as in other secondary batteries using zinc negative electrodes. Methanesulfonic acid electrolytes were introduced in surface finishing several decades ago but their use in flow batteries is only 20 years old. This Review considers the thermodynamics and kinetics of the electrode reactions (desired and secondary) in each half-cell, operational variables, materials for cell components, cell design and performance of the zinc–cerium flow battery. Continuing challenges are highlighted and critical research needs for the science and technological development are considered.