• Bandyopadhyay, Arkamita
• Nayak, Alpana
• Pradhan, Itishree

Abstract

<jats:title>Abstract</jats:title><jats:p>Beyond a critical doping level, Ag–2D TiO<jats:sub>2</jats:sub> sheets (ATO) are deemed to be a flexible transparent conductor, useful for visible‐range functional photonic/optoelectronic devices/sensors, sunlight‐sensitive catalysis, and light‐activated resistive switching. Due to the lack of control of surface energy which often leads to the formation of structural defects and even dimensionality crossover (2D to 0D) of materials during doping reaction, it is challenging to obtain ATO with a controlled doping level. Gauging the urgency, therefore we report the surface energy‐controlled synthesis of ATO employing liquid phase exfoliation of TiO<jats:sub>2</jats:sub> and subsequent hydrothermal Ag‐doping in the presence of Hexamethylenetetramine (HMTA). Electron microscopy and atomic force microscopy reveal ATO sheets with large lateral dimensions. 6‐fold, 4‐fold, and strain‐mediated crystallographic phases of 2D ATO have been revealed by high‐resolution electron imaging. Successful tuning of the band gap down to ~2 eV with Ag doping up to ~10 % is obtained. Synthesized 2D ATO have been investigated for their electrical, optical, optoelectronic, photoluminescence, and ferromagnetic behaviour. Visible light‐sensitive thermally/structurally robust semiconductor/conductor via tuneable doping will pave the way for their flexible as well as wearable device applications. Self‐healing effect of AFM tip‐generated mechanical stress has also been demonstrated.</jats:p>

Topics

• impedance spectroscopy
• surface
• photoluminescence
• atomic force microscopy
• semiconductor
• defect
• electron microscopy
• liquid phase
• surface energy