| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bissett, Mark A.
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Synergistic Improvement in the Thermal Conductivity of Hybrid Boron Nitride Nanotube/Nanosheet Epoxy Compositescitations
- 2024High-performance hybrid glass fibre epoxy composites reinforced with amine functionalised graphene oxide for structural applicationscitations
- 2024Structural Health Monitoring of Scarf Bonded Repaired Glass/Epoxy Laminates Interleaved with Carbon Non-woven Veilcitations
- 2023Tribology of Copper Metal Matrix Composites Reinforced with Fluorinated Graphene Oxide Nanosheets: Implications for Solid Lubricants in Mechanical Switchescitations
- 2023Novel techniques for characterising graphene nanoplatelets using Raman spectroscopy and machine learningcitations
- 2022Joule heating and mechanical properties of epoxy/graphene based aerogel compositecitations
- 2021Effect of graphene nanoplatelets on the mechanical and gas barrier properties of woven carbon fibre/epoxy compositescitations
- 2021Fabrication and Mechanical Performance of Graphene Nanoplatelet/Glass Fiber Reinforced Polymer Hybrid Composites
- 2020Sustainable, high barrier polyaleuritate/nanocellulose biocompositescitations
- 2020Multifunctional Biocomposites Based on Polyhydroxyalkanoate and Graphene/Carbon Nanofiber Hybrids for Electrical and Thermal Applicationscitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored:Via in situ electrochemical atomic force microscopy
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2017Hydrogen Evolution at Liquid|Liquid Interfaces Catalysed by 2D Materialscitations
- 2016Metal-organic framework templated electrodeposition of functional gold nanostructurescitations
- 2016Asymmetric MoS2-graphene-metal sandwiches: Preparation, characterization and applicationcitations
- 2015Tunable doping of graphene nanoribbon arrays by chemical functionalizationcitations
- 2015Synthesis of Lateral Size-Controlled Monolayer 1H-MoS2@Oleylamine as Supercapacitor Electrodes.citations
- 2012Effect of domain boundaries on the Raman spectra of mechanically strained graphenecitations
- 2011Transition from single to multi-walled carbon nanotubes grown by inductively coupled plasma enhanced chemical vapor depositioncitations
Places of action
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article
Hydrogen Evolution at Liquid|Liquid Interfaces Catalysed by 2D Materials
Abstract
The hydrogen evolution reaction (HER) plays a crucial role in clean energy production in hydrogen fuel cells. In order to utilise this process effectively, new catalysts are required that are cheap, non-toxic and efficient. In this context, 2D materials such as transition metal dichalcogenides (e.g. MoS2) should offer the desired properties but have so far proven difficult to manufacture into useful devices. In this work, liquid|liquid interfaces are used for the assembly and testing of the catalytic efficiency of a number of 2D materials and their composites, exploiting the ability of the materials to self-assemble at these interfaces and be tested electrochemically in situ. MoS2, WS2, and graphene were developed for hydrogen evolution at the water|1,2-dichlorobenzene (DCB) interface. The exfoliation process was carried out in DCB and resulted in multi-layer MoS2, few layer WS2 and graphene: when assembled at the water|DCB interface, these materials acted as efficient HER catalysts. HER was investigated using voltammetry, with bulk reaction kinetics monitored by in-situ UV-visible spectroscopy at a constant potential. MoS2 exhibited the highest performance of the catalysts examined, with an average rate constant of 0.0132 ± 0.063 min-1 at an applied Galvani potential of +0.5 V. This is ascribed to the sulphur edge sites of MoS2, which are known to be active for hydrogen evolution predominantly.