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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Brandani, Stefano
University of Edinburgh
in Cooperation with on an Cooperation-Score of 37%
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article
Measurement of Adsorption Properties at Different Scales: from Zero Length Column Experiments on Single Pellets to Breakthrough Curves
Abstract
<jats:title>Abstract</jats:title><jats:p>The ZLC technique is a powerful technique for the measurement of diffusion in nanoporous materials using mg quantities of a sample. Questions remain on whether the measured properties are representative of larger samples. A methodology has been developed to carry out single pellet experiments to determine average properties and variability of equilibrium and kinetic properties. To demonstrate the approach, <jats:italic>n</jats:italic>‐pentane on HISIV3000 extrudates was used as the test system, which was shown to be macropore diffusion controlled. Results on nine pellets provided average values showing a perfect match to breakthrough column experiments with a sample two orders of magnitudes larger.</jats:p>