| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Attfield, Martin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Mixed matrix and thin-film nanocomposite membranes of PIM-1 and hydrolyzed PIM-1 with Ni- and Co-MOF-74 nanoparticles for CO 2 separation: Comparison of blending, grafting and crosslinking fabrication methodscitations
- 2023Breathing Behaviour Modification of Gallium MIL‐53 Metal–Organic Frameworks Induced by the Bridging Framework Inorganic Anioncitations
- 2021Crystal growth of the core and rotated epitaxial shell of a heterometallic metal-organic framework revealed with atomic force microscopycitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworks
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworkscitations
- 2017Predicting crystal growth via a unified kinetic three-dimensional partition modelcitations
- 2016Metal-organic framework templated electrodeposition of functional gold nanostructurescitations
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article
Breathing Behaviour Modification of Gallium MIL‐53 Metal–Organic Frameworks Induced by the Bridging Framework Inorganic Anion
Abstract
<jats:title>Abstract</jats:title><jats:p>Controlling aspects of the μ<jats:sub>2</jats:sub>‐X<jats:sup>−</jats:sup> bridging anion in the metal–organic framework Ga‐MIL‐53 [GaX(bdc)] (X<jats:sup>−</jats:sup>=(OH)<jats:sup>−</jats:sup> or F<jats:sup>−</jats:sup>, bdc=1, 4‐benzenedicarboxylate) is shown to direct the temperature at which thermally induced breathing transitions of this framework occur. In situ single crystal X‐ray diffraction studies reveal that substituting 20 % of (OH)<jats:sup>−</jats:sup> in [Ga(OH)(bdc)] (<jats:bold>1</jats:bold>) for F<jats:sup>−</jats:sup> to produce [Ga(OH)<jats:sub>0.8</jats:sub>F<jats:sub>0.2</jats:sub>(bdc)] (<jats:bold>2</jats:bold>) stabilises the large pore (lp) form relative to the narrow pore (np) form, causing a well‐defined decrease in the onset of the lp to np transition at higher temperatures, and the adsorption/desorption of nitrogen at lower temperatures through np to lp to intermediate (int) pore transitions. These in situ diffraction studies have also yielded a more plausible crystal structure of the int‐[GaX(bdc)] ⋅ H<jats:sub>2</jats:sub>O phases and shown that increasing the heating rate to a flash heating regime can enable the int‐[GaX(bdc)] ⋅ H<jats:sub>2</jats:sub>O to lp‐[GaX(bdc)] transition to occur at a lower temperature than np‐[GaX(bdc)] via an unreported pathway.</jats:p>