693.932 PEOPLE
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Avarvari, Narcis
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Topics
Publications (31/31 displayed)
- 2024A highly conducting tetrathiafulvalene-tetracarboxylate based dysprosium(iii) 2D metal-organic framework with single molecule magnet behaviourcitations
- 2023Spin-dependent electrochemistry and electrochemical enantioselective recognition with chiral methylated bis(ethylenedithio)-tetrathiafulvalenescitations
- 2023Bis(Vinylenedithio)‐Tetrathiafulvalene‐Based Coordination Networkscitations
- 2022[4]Helicene based anions in electrocrystallization with tetrachalcogenafulvalene donors †citations
- 2022Zinc(II) and copper(II) complexes with benzothiadiazole Schiff-base ligands †citations
- 2022Helical thienothiophene (TT) and benzothieno–benzothiophene (BTBT) derivatives: synthesis, structural characterization and semiconducting propertiescitations
- 2021Combined Experimental/Theoretical Study on the Luminescent Properties of Homoleptic/Heteroleptic Erbium(III) Anilate-Based 2D Coordination Polymerscitations
- 2021Old Donors for New Molecular Conductors: Combining TMTSF and BEDT-TTF with Anionic (TaF6)1−x/(PF6)x Alloyscitations
- 2021Conducting chiral nickel(ii) bis(dithiolene) complexes : Structural and electron transport modulation with the charge and the number of stereogenic centrescitations
- 2021Conducting chiral nickel( ii ) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centrescitations
- 2021Conducting chiral nickel(II) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres
- 2020Chiral Conducting Me-EDT-TTF and Et-EDT-TTFBased Radical Cation Salts with the Perchlorate Anion
- 2020Combining Chirality and Hydrogen Bonding in Methylated Ethylenedithio-Tetrathiafulvalene Primary Diamide Precursors and Radical Cation Saltscitations
- 2020Conservation of structural arrangements and 3 : 1 stoichiometry in a series of crystalline conductors of TMTTF, TMTSF, BEDT-TTF, and chiral DM-EDT-TTF with the oxo-bis[pentafluorotantalate( v )] dianioncitations
- 2020Chiral Conducting Me-EDT-TTF and Et-EDT-TTF-Based Radical Cation Salts with the Perchlorate Anioncitations
- 2020In Search of Chiral Molecular Superconductors: κ‐[( S,S )‐DM‐BEDT‐TTF] 2 ClO 4 Revisitedcitations
- 2020Conservation of structural arrangements and 3 : 1 stoichiometry in a series of crystalline conductors of TMTTF, TMTSF, BEDT-TTF, and chiral DM-EDTTTF with the oxo-bis[pentafluorotantalate(V)] dianion
- 2019Chiral EDT-TTF precursors with one stereogenic centre: substituent size modulation of the conducting properties in the (R-EDT-TTF)2PF6 (R = Me or Et) series
- 2019Chiral EDT-TTF precursors with one stereogenic centre: substituent size modulation of the conducting properties in the (R-EDT-TTF) 2 PF 6 (R = Me or Et) seriescitations
- 2018Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networks
- 2017Synthesis and Physical Properties of Purely Organic BEDT-TTF-Based Conductors Containing Hetero-/Homosubstituted Cl/CN-Anilate Derivativescitations
- 2017Synthesis and physical properties of purely organic BEDT-TTF-based conductors containing hetero-/homosubstituted Cl/CN-anilate derivativescitations
- 2016Localization versus delocalization in chiral single component conductors of gold bis(dithiolene) complexescitations
- 2015Structural, photophysical and magnetic properties of transition metal complexes based on the dipicolylamino-chloro-1,2,4,5-tetrazine ligandcitations
- 2015Complete series of chiral paramagnetic molecular conductors based on tetramethyl-bis(ethylenedithio)-tetrathiafulvalene (TM-BEDT-TTF) and chloranilate-bridged heterobimetallic honeycomb layerscitations
- 2014Structural Diversity and Physical Properties of Paramagnetic Molecular Conductors Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and the Tris(chloranilato)ferrate(III) Complexcitations
- 2014Electrical magnetochiral anisotropy in a bulk chiral molecular conductorcitations
- 2013Chirality Driven Metallic versus Semiconducting Behavior in a Complete Series of Radical Cation Salts Based on Dimethyl-Ethylenedithio-Tetrathiafulvalene (DM-EDT-TTF)citations
- 2012Bimetallic neutral palladium (II) bis(dithiolene) complex: Unusual synthesis, structural and theoretical studycitations
- 2012Cyanomethylene-bis(phosphonate) as ditopical ligand: stepwise formation of a 2-D heterometallic Fe(III)-Ag(I) coordination networkcitations
- 2010Order versus disorder in chiral tetrathiafulvalene-oxazoline radical-cation salts: structural and theoretical investigations and physical properties.citations
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article
Bis(Vinylenedithio)‐Tetrathiafulvalene‐Based Coordination Networks
Abstract
International audience ; Novel coordination polymers embedding electroactive moieties present a high interest in the development of porous conducting materials. While tetrathiafulvalene (TTF) based metal-organic frameworks were reported to yield through-space conducting frameworks, the use of S-enriched scaffolds remains elusive in this field. Herein is reported the employment of bis(vinylenedithio)tetrathiafulvalene (BVDT-TTF) functionalized with pyridine coordinating moieties in coordination polymers. Its combination with various transition metals yielded four isostructural networks, whose conductivity increased upon chemical oxidation with iodine. The oxidation was confirmed in a singlecrystal to single-crystal X-ray diffraction experiment for the Cd(II) complex. Raman spectroscopy measurements and DFT calculations confirmed the oxidation state of the bulk materials, and band structure calculations assessed the ground state as an electronically localized antiferromagnetic state, while the conduction occurs in a 2D manner. These results are shedding light to comprehend how to improve through-space conductivity thanks to sulfur enriched ligands.