| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Saha, Rajat
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivitycitations
- 2024A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)2]n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 Kcitations
- 2024Simultaneous hydroxido-, nitrato-, and phenoxido-bridged binuclear copper Schiff base complex for green catalytic click chemistry: Synthesis, structure, Hirshfeld surface analysis, theoretical study and photoluminescence spectracitations
- 2024Carbazole diester strapped calix[4]pyrrole: Synthesis, anion binding and self-assembly based on ion pair recognitioncitations
- 2024Rhodamine hydrazide-linked naphthalimide derivative: Selective naked eye detection of Cu2+, S2− and understanding the therapeutic potential of the copper complex as an anti-cervical cancer agentcitations
- 2023Electrocatalytic Water Oxidation by Hydrolytically Stable Metal‐Organic Frameworks at Both Neutral and Alkaline Medium: Inverse Relation of Dimensionality with Catalytic Activitycitations
- 2023Multifunctional Interpenetrated 3D Supramolecular Structure Based on 1D Coordination Polymers: Selective Adsorption, Magnetism, Optical Property, Theoretical Analysis, and Electrical Conductivitycitations
- 2023A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)2]n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 Kcitations
- 2022Simultaneous presence of mono- and bi-cationic bipyridyls within a metal-organic supramolecular host: crystal structure, spectral and Hirshfeld surface analysiscitations
- 2022Solvent‐ and Substrate‐Induced Chiroptical Inversion in Amphiphilic, Biocompatible Glycoconjugate Supramolecules: Shape‐Persistent Gelation, Self‐Healing, and Antibacterial Activitycitations
- 2021Photo-responsive Schottky Diode Behavior of a Donor-Acceptor Co-crystal with Violet Blue Light Emissioncitations
- 2014Synthesis, characterization, X-ray crystallography and antimicrobial activities of new Co(III) and Cu(II) complexes with a pyrazole based Schiff base ligandcitations
Places of action
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article
Solvent‐ and Substrate‐Induced Chiroptical Inversion in Amphiphilic, Biocompatible Glycoconjugate Supramolecules: Shape‐Persistent Gelation, Self‐Healing, and Antibacterial Activity
Abstract
<jats:title>Abstract</jats:title><jats:p>We have shown solvent‐ and substrate‐dependent chiral inversion of a few glycoconjugate supramolecules. (<jats:italic>Z</jats:italic>)‐F‐Gluco, in which <jats:sc>d</jats:sc>‐glucosamine has been attached chemically to Cbz‐protected <jats:sc>l</jats:sc>‐phenylalanine at the C terminus, forms a self‐healing hydrogel through intertwining of the nanofibers wherein the gelators undergo lamellar packing in the β‐sheet secondary structures with a single chiral handedness. Dihybrid (<jats:italic>Z</jats:italic>)‐F‐gluco nanocomposite gel was prepared by in‐situ formation of silver nanoparticles AgNPs in the gel; this enhances the mechanical properties of the composite gel through physical crosslinking without altering the packing pattern. In contrast, (<jats:italic>Z</jats:italic>)‐L‐gluco bearing an <jats:sc>l</jats:sc>‐leucine moiety does not form a hydrogel but an organogel. Interestingly, the chiral handedness of the aggregates of (<jats:italic>Z</jats:italic>)‐L‐gluco can be reversed by choosing suitable solvents. In addition to self‐healing behavior, (<jats:italic>Z</jats:italic>)‐L‐gluco gel revealed shape persistency. Further, (<jats:italic>Z</jats:italic>)‐F‐gluco hydrogel is benign, nontoxic, non‐immunogenic, and non‐allergenic in animal cells. AgNP‐loaded (<jats:italic>Z</jats:italic>)‐F‐gluco hydrogel showed antibacterial activity against both Gram‐positive and Gram‐negative bacteria.</jats:p>