| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Lee, Arie Van Der
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2022Synthesis and structural characterization of new ladder-like organostannoxanes derived from carboxylic acid derivatives: [C<sub>5</sub>H<sub>4</sub>N(<i>p</i>-CO<sub>2</sub>)]<sub>2</sub>[Bu<sub>2</sub>Sn]<sub>4</sub>(<i>μ</i> <sub> <i>3</i> </sub>-O)<sub>2</sub>(<i>μ</i> <sub> <i>2</i> </sub>-OH)<sub>2</sub>, [Ph<sub>2</sub>CHCO<sub>2</sub>]<sub>4</sub>[Bu<sub>2</sub>Sn]<sub>4</sub>(<i>μ</i> <sub> <i>3</i> </sub>-O)<sub>2</sub>, and [(<i>p</i>-NH<sub>2</sub>)-C<sub>6</sub>H<sub>4</sub>-CO<sub>2</sub>]<sub>2</sub>[Bu<sub>2</sub>Sn]<sub>4</sub>(<i>μ</i> <sub> <i>3</i> </sub>-O)<sub>2</sub>(<i>μ</i> <sub> <i>2</i> </sub>-OH)<sub>2</sub>citations
- 2022The Unexpected Helical Supramolecular Assembly of a Simple Achiral Acetamide Tecton Generates Selective Water Channelscitations
- 2019High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1citations
- 2012Relationship between wood elastic strain under bending and cellulose crystal straincitations
- 2003X-ray reflectometry characterization of SON 68 glass alteration films
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article
The Unexpected Helical Supramolecular Assembly of a Simple Achiral Acetamide Tecton Generates Selective Water Channels
Abstract
Achiral 2-hydroxy-N-(diphenylmethyl)acetamide (HNDPA) crystallizes in the P61 chiral space group as a hydrate, building up permeable chiral crystalline helical water channels. The crystallization driven chiral self-resolution process is highly robust, with the same air stable crystalline form readily obtained from a variety of conditions. Interestingly, the HNDPA supramolecular helix inner pore is filled by a helical water wire. The whole edifice is mainly stabilized by robust hydrogen bonds involving the HNDPA amide bonds and CH…π interactions between the HNDPA phenyl groups. The crystalline structure shows a breathing behavior, with completely reversible release and reuptake of water inside the chiral channel, under ambient conditions. Importantly, the HNDPA channel is able to transport water very efficiently and selectively in biomimetic conditions. With a permeability per channel of 3.3 million water molecules per second in large unilamellar vesicles (LUV) and a total selectivity against NaCl, the HNDPA channel is a very promising functional nanomaterial for future applications.