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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jones, Matthew D.
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2019Copolymerization of Cyclic Phosphonate and Lactide: Synthetic Strategies toward Control of Amphiphilic Microstructurecitations
- 2018Bipyrrolidine salan alkoxide complexes of lanthanides: synthesis, characterisation, activity in the polymerisation of lactide and mechanistic investigation by DOSY NMRcitations
- 2017Synthesis of PLGA using a C3-symmetric Zr (IV) amine tris(phenolate) alkoxide initiator and the effects of gamma radiation on its propertiescitations
- 2017Zirconium amine tris(phenolate):A more effective initiator for biomedical lactidecitations
- 2017Zirconium amine tris(phenolate)citations
- 2017Zn<sup>II</sup> Chlorido Complexes with Aliphatic, Chiral Bisguanidine Ligands as Catalysts in the Ring‐Opening Polymerisation of <i>rac</i>‐Lactide Using FT‐IR Spectroscopy in Bulkcitations
- 2016Aminopiperidine based complexes for lactide polymerisationcitations
- 2013Synergistic empirical and theoretical study on the stereoselective mechanism for the aluminum salalen complex mediated polymerization of rac-Lactidecitations
- 2011Homopiperazine and piperazine complexes of Zr(IV) and Hf(IV) and their application to the ring-opening polymerisation of lactidecitations
- 2011Salalen aluminium complexes and their exploitation for the ring opening polymerisation of rac-lactidecitations
- 2009Synthesis and structure of aluminium amine-phenolate complexescitations
- 2009Novel Ti(IV) and Zr(IV) complexes and their application in the ring-opening polymerisation of cyclic esterscitations
- 2006Synthesis and X-ray structures of new titanium(IV) aryloxides and their exploitation for the ring opening polymerization of epsilon-caprolactonecitations
- 2003trans-bis[(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2]palladium(II) dichloride methanol trisolvate
- 2003(η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonatecitations
- 2003(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate
- 2003[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvatecitations
- 2003(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvatecitations
Places of action
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article
Synergistic empirical and theoretical study on the stereoselective mechanism for the aluminum salalen complex mediated polymerization of rac-Lactide
Abstract
Open your ring: Aluminum salalen complexes are used to initiate the ring-opening polymerization (ROP) of rac-lactide (LA). The reaction pathway of the LA isomers was elucidated by a detailed computational study, which revealed that small changes in the catalytic “bag” implicate the change in induced tacticity (see scheme; PLA= polylactide).