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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Kočí, Jan | Prague |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Tuci, Giulia
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article
Thin Coatings of Polymer of Intrinsic Microporosity (PIM-1) Enhance Nickel Electrodeposition and Nickel-Catalyzed Hydrogen Evolution
Abstract
Nickel nanoparticle electrodeposition is studied on flat glassy carbon (GC) or on nitrogen-doped reduced graphene oxide (rGO-N) substrates. The effects of a very thin (nominally 16 nm) layer polymer of intrinsic microporosity (PIM-1) are investigated (i) on enhancing nickel nanoparticle nucleation and growth during electrodeposition and (ii) on enhancing hydrogen evolution electrocatalysis. Beneficial effects are tentatively assigned to PIM-1 suppressing blocking effects from interfacial hydrogen bubble formation. Exploratory data suggest that in aqueous 0.5 M NaCl solution (artificial seawater) nickel nanoparticles grown into a thin film of PIM-1 could be a viable electrocatalyst with an onset of hydrogen evolution only slightly negative compared to that observed for platinum nanoparticles.