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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tetteh, Emmanuel Batsa
Ruhr University Bochum
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Combinatorial screening of electronic and geometric effects in compositionally complex solid solutions toward a rational design of electrocatalystscitations
- 2023Combinatorial screening of electronic and geometric effects in compositionally complex solid solutions toward a rational design of electrocatalysts
- 2023Long‐range SECCM enables high‐throughput electrochemical screening of high entropy alloy electrocatalysts at up‐to‐industrial current densitiescitations
- 2023Scrutinizing intrinsic oxygen reduction reaction activity of a Fe−N−C catalyst via scanning electrochemical cell microscopycitations
- 2023Acidic hydrogen evolution electrocatalysis at high‐entropy alloys correlates with its composition‐dependent potential of zero chargecitations
- 2023Reassessing the intrinsic hydrogen evolution reaction activity of platinum using scanning electrochemical cell microscopycitations
- 2023Microscale combinatorial libraries for the discovery of high-entropy materialscitations
- 2023Reorganization energy in a polybromide ionic liquid measured by scanning electrochemical cell microscopycitations
- 2022Zooming‐in - visualization of active site heterogeneity in high entropy alloy electrocatalysts using scanning electrochemical cell microscopycitations
Places of action
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article
Scrutinizing intrinsic oxygen reduction reaction activity of a Fe−N−C catalyst via scanning electrochemical cell microscopy
Abstract
Carbon-based nanomaterials are renowned for their exceptional properties, making them propitious candidates for oxygen reduction reaction (ORR) electrocatalysis. However, their intrinsic activity is often challenging to investigate unambiguously with conventional methodologies due to the inherent complexities of such systems and the material itself. Zooming into the material and gaining electrochemical information with high resolution is a way to get rid of many experimental factors that influence the catalytic activity in macro-scale measurements. Herein, we employ nano-scale scanning electrochemical cell microscopy (SECCM) to investigate individual catalyst agglomerates with and without Nafion content. The intrinsic ORR activity of the catalyst was unravelled by using a unique approach of normalizing the data of all measured points by their distinctive electrochemical surface area (ECSA). When coupling with scanning electron microscopy (SEM), the structure and morphology of the catalytically active agglomerates were visualized.