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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Coutanceau, Christophe
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Mo2CTx MXene supported nickel-iron alloy: an efficient and stable heterostructure to boost oxygen evolution reactioncitations
- 2023Zirconium-based nanocatalysts by sputtering onto glycerol and solid carbon
- 2023Mo2CTx MXene supported nickel-iron alloy: an efficient and stable heterostructure to boost oxygen evolution reaction.citations
- 2022Electroreforming of glucose/xylose mixtures on PdAu based nanocatalystscitations
- 2021Binary and ternary Pt-based clusters grown in a plasma multimagnetron-based gas aggregation source: electrocatalytic evaluation towards glycerol oxidationcitations
- 2018Conductive Polymer Grafting Platinum Nanoparticles as Efficient Catalysts for the Oxygen Reduction Reaction: Influence of the Polymer Structurecitations
- 2017A new etching environment (FeF$_3$/HCl) for the synthesis of two-dimensional titanium carbide MXenes: a route towards selective reactivity vs. watercitations
- 2015Low-temperature growth processes with helicon radio-frequency plasmas. TiO2 films and Pt/C nano-clusters
- 2013Pt nanoclusters prepared by magnetron sputtering and cluster beam deposition for proton exchange membrane fuel cell
- 2013One-step synthesis and chemical characterization of Pt C nanowire composites by plasma sputteringcitations
- 2011PdAu/C catalysts prepared by plasma sputtering for the electro-oxidation of glycerolcitations
- 2006Methoxy methane (dimethyl ether) as an alternative fuel for direct fuel cellscitations
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article
Electroreforming of glucose/xylose mixtures on PdAu based nanocatalysts
Abstract
The electro-reforming of glucose/xylose mixtures has been evaluated at Pd1-xAux/C anodes in 0.10 mol L-1 NaOH electrolyte. The catalysts synthesized by a wet chemistry route are comprehensively characterized by physicochemical and electrochemical techniques. From linear scan voltammetry and insitu Fourier transform infrared spectroscopy measurements, it was shown that the Pd0.3Au0.7/C material led to the best electrocatalytic behavior towards the electrooxidation of glucose/xylose mixtures in terms of activity (higher current densities at lower potentials) and selectivity (lower dissociative adsorption). Six-hour chronoamperometry measurements were performed at 293 K in a 25 cm 2 electrolysis cell at +0.4 V and +0.6 V and the reaction products were analyzed by high performance liquid chromatography. The main products were gluconate and xylonate, but the contributions of xylose to the whole products formed was always lower in percentages than the initial xylose ratios in solutions, showing that glucose was more electro-reactive than xylose at Pd0.3Au0.7 surface.