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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Morais, Cláudia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023Mo2CTx MXene supported nickel-iron alloy: an efficient and stable heterostructure to boost oxygen evolution reactioncitations
- 2023Mo2CTx MXene supported nickel-iron alloy: an efficient and stable heterostructure to boost oxygen evolution reaction.citations
- 2022An FTIR study of the electrooxidation of C2 and C3 alcohols on carbon-supported PdxRhy in alkaline mediumcitations
- 2022Tuning the Tin Oxide-Carbon Composite Support to Deposit Rh Nanoparticles for Glycerol-to-Carbonate Electro-Conversioncitations
- 2022A step forward: hydrogen production on cobalt molybdenum sulfide electrocatalyst in anion exchange membrane water electrolyzercitations
- 2020Insight into the Electrooxidation Mechanism of Ethylene Glycol on Palladium‐Based Nanocatalysts: In Situ FTIRS and LC‐MS Analysiscitations
- 2020On a Two-Dimensional MoS2 /Mo2CTx Hydrogen Evolution Catalyst Obtained by the Topotactic Sulfurization of Mo2CTx MXenecitations
- 2019MXene Supported Cobalt Layered Double Hydroxide Nanocrystals: Facile Synthesis Route for a Synergistic Oxygen Evolution Reaction Electrocatalystcitations
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article
Insight into the Electrooxidation Mechanism of Ethylene Glycol on Palladium‐Based Nanocatalysts: In Situ FTIRS and LC‐MS Analysis
Abstract
<jats:title>Abstract</jats:title><jats:p>The ethylene glycol oxidation reaction on nickel and ruthenium modified palladium nanocatalysts was investigated with electrochemical, spectroelectrochemical, and chromatographic methods. These carbon‐supported materials, prepared by a revisited polyol approach, exhibited high activity towards the ethylene glycol electrooxidation in alkaline medium. Electrolysis coupled with high performance liquid chromatography/mass spectrometry (HPLC‐MS) and in situ Fourier transform infrared spectroscopy (FTIRS) measurements allowed us to determine the different compounds electrogenerated in the oxidative conversion of this two‐carbon molecule. High value‐added products such as oxalate, glyoxylate, and glycolate were identified in all electrolytic solutions, whereas glyoxylate was selectively formed at the Ru<jats:sub>45</jats:sub>@Pd<jats:sub>55</jats:sub>/C electrode surface. In situ FTIRS results also showed a decrease in the pH value in the thin layer near the electrode as a consequence of OH<jats:sup>−</jats:sup> consumption during the spectroelectrochemical experiments.</jats:p>